36957-84-3Relevant articles and documents
(Dicyclopentadiene) platinum(II) dichloride: An efficient catalyst for the hydrosilylation reaction between alkenes and triethoxysilane
Wu, Huarui,Zheng, Chaoyue,Chen, Naiwu,Zhu, Jie,Gao, Deqing
supporting information, p. 1576 - 1578 (2017/04/03)
(Dicyclopentadiene) platinum(II) dichloride was found to be an efficient hydrosilylation catalyst (homogeneous) upon a wide variety of functionalized alkenes and alkenes terminated with chemical moieties (diphenyl amino-, N-carbazol- and N-isoindoline-1,3-dione-). It is noteworthy that the hydrosilylation of aminated alkenes with triethoxysilane exhibited the yield of over 70% and the selectivity (γ-isomer/β-isomer) of more than 3/1. Due to steric hindrance lowering Markovnikov probability, the alkenes with big terminal moieties (diphenyl amino-, N-carbazol- and N-isoindoline-1,3-dione-) presented the high ratio of anti-Markovnikov isomers. The strategy of the hydrosilylation of the protected diamino chelating alkene was developed.
The influence of additives to the Speier catalyst on hydrosilylation of functionalized alkenes
Chernyshev,Belyakova,Knyazeva,Pomerantseva,Efimova
, p. 1374 - 1378 (2007/10/03)
Hydrosilylation of several unsaturated compounds with triethoxysilane in the presence of the Speier catalyst with various additives influencing the reaction rate and selectivity was studied. The mechanism of hydrosilylation is discussed.