3711-51-1

Basic information

• Product Name: diethyl phosphorochloridothionate
• Synonyms: diethyl phosphorochloridothionate
• CAS NO: 3711-51-1
• Molecular Weight: 188.615
• Mol File: 3711-51-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diethyl phosphorochloridothionate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl phosphorochloridothionate(3711-51-1)
• EPA Substance Registry System: diethyl phosphorochloridothionate(3711-51-1)

Safety Data

• Hazardous Substances Data: 3711-51-1(Hazardous Substances Data)

Upstream product

• 1186-09-0 O,O,S-triethyl phosphorothioate 

Downstream Products

• 40992-40-3 2-(Ethoxy-ethylsulfanyl-phosphoryloxy)-benzoic acid methyl ester 
• 40992-34-5 4-(Ethoxy-ethylsulfanyl-phosphoryloxy)-benzoic acid ethyl ester 

Relevant articles and documents

Reaction of Thiolo and Selenolo Esters of Phosphorus Acids with Halogens. Part 3. Interaction of O,O,S-Trialkyl Phosphorothioates and O,S-Dialkyl t-Butylphosphonothioates with Sulphuryl Chloride and Halogens

The reaction of the title phosphono- and phosphoro-thiolates with sulphuryl chloride and halogens involves in every case the formation of intermediates containing two phosphorus atoms >P+(SR)OP(O)- (X = SO2Cl or halogen).The formation of the latter in the course of chlorinolysis of phosphorus thiolesters is suggested to be responsible for the occurrence of a mechanism involving retention of configuration.The effect of the structure of the reactants and the nature of solvent on the reaction stereochemistry is discussed.