37338-40-2

Basic information

• Product Name: dodec-8-enyl acetate
• Synonyms: dodec-8-enyl acetate;8-dodecenyl acetate;8-Dodecen-1-ol acetate;Acetic acid 8-dodecenyl ester;107874-02-2 (Denacyl);Einecs 253-469-0
• CAS NO: 37338-40-2
• Molecular Formula: C₁₄H₂₆O₂
• Molecular Weight: 226.35504
• EINECS: 253-469-0
• Mol File: 37338-40-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 300.1°Cat760mmHg
• Flash Point: 96.5°C
• Appearance: /
• Density: 0.881g/cm³
• Vapor Pressure: 0.00114mmHg at 25°C
• Refractive Index: 1.448
• CAS DataBase Reference: dodec-8-enyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: dodec-8-enyl acetate(37338-40-2)
• EPA Substance Registry System: dodec-8-enyl acetate(37338-40-2)

Safety Data

• Hazardous Substances Data: 37338-40-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H26O2/c1-3-4-5-6-7-8-9-10-11-12-13-16-14(2)15/h5-6H,3-4,7-13H2,1-2H3

Upstream product

• 153123-34-3 Δ⁸-dodecen-1-ol 
• 108-24-7 acetic anhydride 
• 55695-90-4 2-(9-bromononyloxy)tetrahydropyran 
• 55362-80-6 9-bromononan-1-ol 
• 13175-42-3 2-non-8-enyloxy-tetrahydro-pyran 
• 1146096-85-6 9-hydroxynon-1-yl 4-methylbenzenesulfonate 
• 3937-56-2 1,9-Nonanediol 
• 98398-50-6 (Z)-1-(2-tetrahydropyranyloxy)dodec-8-ene 
• 67700-26-9 oct-4-en-1-ol 
• 1072-60-2 2-vinyltetrahydrofuran 
• 40596-44-9 4-iodobutyl acetate 
• 42976-83-0 1-bromooct-4-ene 

Relevant articles and documents

SYNTHESIS OF PHEROMONES AND RELATED MATERIALS VIA OLEFIN METATHESIS

Methods for preparation of olefins, including 8- and 11-unsaturated monoenes and polyenes, via transition metathesis-based synthetic routes are described. Metathesis reactions in the methods are catalyzed by transition metal catalysts including tungsten-, molybdenum-, and ruthenium-based catalysts. The olefins include insect pheromones useful in a number of agricultural applications.

Ethylation of 2-Alkenyltetrahydrofurans and 2-Alkenyltetrahydropyrans Catalyzed by Titaniun(IV) Isoprpopoxide. Supplement to the Synthesis of Pheromones of Lesser Plum Worm and Tea Leaf Roller Moth

Reaction of 2-vinyltetrahydrofuran and 2-vinyltetrahydropyran with ethylmagnesium bromude in the presence ot titanium(IV) isopropoxide afforded in moderate selectivity trans-4-octen-1-ol and trans-5-nonen-1-ol respectively. Best yields and high stereochemical purity of products were obtained in ethylation under these conditions of 2-(cis-1-propenyl)tetrahydrofuran, 2-(cis-1-proprnyl)- and 2-(trans-1-propenyl)-tetrahydropyran. It is assumed that the key organometallic intermediate formed was diisopropoxytitanacycloprpopane, and direction of its addition to the doubel bond governed the streochemistry of the resulting product. The obtained trans-4-octen-1-ol and trans-7-methyl-5-nonen-1-ol were applied as initial products in the synthesis of sex pheromones of lesser plum worm (Grafolita funebrana) and tea leaf roller moth (Adoxophyes sp).