3743-22-4Relevant articles and documents
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Agashe,Jose
, p. 1227,1230 (1977)
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Asymmetric Transfer Hydrogenation of 1,3-Alkoxy/Aryloxy Propanones Using Tethered Arene/Ru(II)/TsDPEN Complexes
Forshaw, Sam,Matthews, Alexander J.,Brown, Thomas J.,Diorazio, Louis J.,Williams, Luke,Wills, Martin
supporting information, p. 2789 - 2792 (2017/06/07)
A series of propanones containing combinations of aryloxy and alkoxy substituents at the 1- and 3-positions were reduced to the alcohols via asymmetric transfer hydrogenation using a tethered Ru(II)/TsDPEN catalyst. The enantioselectivities of the reductions reveal a complex pattern of electronic and steric effects which, when used in a matched combination, can lead to the formation of products of up to 68% ee (84:16 er) from this highly challenging class of substrate.
Neutral 1,3-diindolylureas for nerve agent remediation
Barba-Bon, Andrea,Costero, Ana M.,Parra, Margarita,Gil, Salvador,Martínez-Má?ez, Ram?n,Sancen?n, Félix,Gale, Philip A.,Hiscock, Jennifer R.
supporting information, p. 1586 - 1590 (2013/02/25)
Efficient neutralization of nerve-agent simulants by 1,3-diindolylureas in a neutral medium was investigated (see scheme; DCP=diethylchlorophosphate, DCNP=diethylcyanophosphonate). The rate of hydrolysis of the simulants was found to increase by as much as 45 % in the presence of these compounds. A mechanism based on the simulant complexation was established. Copyright
