3744-29-4Relevant articles and documents
Quenching of CHF 1A'' (0,02 after Single Vibronic Level Excitation by the Diatomic Molecules H2, O2 and CO
Dornhoefer, G.,Hack, W.
, p. 485 - 490 (2007/10/02)
The elementary deactivation processes of CHF(, v'2) by H2(X1Σg+), O2(X3Σg-, and CO(X1Σ+) were studied in a quasistatic photolysis chamber.Determination of time and spectrally resolved laser-induced fluorescence of CHF (1A'', v'2) in single vibronic excited levels (SVL) (0 2 1A' (0,0,0)> was generated in the fluorescence cell by multiphoton dissociation (MPD) of CH2F2.The overall CHF(, v'2)-depletion rate constants: .Asignificant increase of the rate constants for higher vibronic states was observed.The contribution of vibration deactivation to the overall depletion of the initially excited state was found to be small (2 = 1 and Δv'2 = 2 respectively.The reaction mechanisms are discussed. - Keywords: Elementary Reactions / Energy Transfer / Photochemistry
