3763-51-7

Basic information

• Product Name: Cyclohexanone, 2-(1,1-dimethylethyl)-, (2R)-
• CAS NO: 3763-51-7
• Molecular Formula: C10H18O
• Molecular Weight: 154.252
• Mol File: 3763-51-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-(1,1-dimethylethyl)-, (2R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-(1,1-dimethylethyl)-, (2R)-(3763-51-7)
• EPA Substance Registry System: Cyclohexanone, 2-(1,1-dimethylethyl)-, (2R)-(3763-51-7)

Safety Data

• Hazardous Substances Data: 3763-51-7(Hazardous Substances Data)

Upstream product

• 1728-46-7 2-tert-butylcyclohexanone 
• 33993-53-2 N,S-dimethyl-S-phenylsulfoximine 
• 92207-91-5 C₁₈H₂₉NO₂S 
• 5448-22-6 trans-2-tert-butylcyclohexan-1-ol 
• 13492-07-4 (+)-(1S,2R)-2-(tert-butyl)cyclohexanol 

Relevant articles and documents

Secondary Phosphine Oxides as Multitalented Preligands En Route to the Chemoselective Palladium-Catalyzed Oxidation of Alcohols

Secondary phosphine oxides O=PHR2 (SPOs) were identified as multitalented preligands for the chemoselective Pd-catalyzed oxidation of alcohols by a hydrogen-abstracting methodology. SPOs were found to promote the hydrogen-abstraction step as well as hydrogen transfer to a Michael acceptor by generating a putative active H?Pd species. The catalytic system operates under neutral conditions and was proven to be compatible with various electrophilic and nucleophilic functionalities within the substrates as well as water- and air-sensitive functional groups.