37677-93-3Relevant articles and documents
Polymerization kinetics of adamantane-based dicyanate ester and thermal properties of resulting polymer
Galukhin, Andrey,Islamov, Daut,Nikolaev, Ilya,Nosov, Roman,Taimova, Guzel,Vyazovkin, Sergey
, (2021)
The kinetics of liquid-state polymerization of adamantane-based dicyanate ester has been studied for the first time by means of conventional and temperature-modulated DSC. It has been detected that the later stages of polymerization undergo a transition from kinetic- to diffusion-controlled regime. Detailed analysis of the polymerization kinetics in the reaction-controlled regime has revealed that the process rate can be well described in the frameworks of the presently proposed autocatalytic quasi-one-step model. The proposed model eliminates arbitrarily guessing the value for the initial conversion that provides a reasonable alternative to the broadly used truncated Sestak-Berggren model. The adamantane-based dicyanate ester polymerization product demonstrates markedly higher thermal stability and glass transition temperature compared to those of dicyanate esters with flexible hydrocarbon bridging units. The obtained experimental results confirm our hypothesis about the influence of the rigidity of cyanate ester molecule on its reactivity and thermal properties of the corresponding polymer product.
Organic compound, electronic component and electronic device
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Paragraph 0173-0177, (2020/09/20)
The invention belongs to the technical field of organic materials, and particularly provides an organic compound which is of a structure formed by taking adamantyl as a core and connecting two nitrogen-containing heteroaryl groups to adamantane through a connecting group. The compound is suitable for being applied to an electron transport layer of an electronic component. The invention also provides an electronic component and an electronic device comprising the compound. The organic compound can improve the electron transport performance of the electronic component.
Cyanate ester compound, curable resin composition containing the same, and hardened product thereof
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Page/Page column 38-39, (2018/04/25)
The present invention is a cyanate ester compound represented by the following formula (1): wherein Ar represents an aromatic ring; R1 each independently represents a hydrogen atom, an alkyl group, or an aryl group; n each independently represe