3768-56-7

Basic information

• Product Name: 1-(TRIMETHYLSILYL)PIPERIDINE
• Synonyms: N-TRIMETHYLSILYLPIPERIDINE;TRIMETHYLSILYLPIPERIDINE;1-(TRIMETHYLSILYL)PIPERIDINE;1-(trimethylsilyl)-piperidin;Piperidine,1-(trimethylsilyl)-;trimethyl(piperidin-1-yl)silane;trimethyl(piperidino)silane;(N-PIPERIDINO)TRIMETHYLSILANE
• CAS NO: 3768-56-7
• Molecular Formula: C₈H₁₉NSi
• Molecular Weight: 157.33
• EINECS: 223-198-2
• Mol File: 3768-56-7.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 193 °C at 760 mmHg
• Flash Point: 70.5 °C
• Appearance: /
• Density: 0.85 g/cm³
• Vapor Pressure: 0.662mmHg at 25°C
• Refractive Index: 1.45
• PKA: 11.23±0.20(Predicted)
• CAS DataBase Reference: 1-(TRIMETHYLSILYL)PIPERIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(TRIMETHYLSILYL)PIPERIDINE(3768-56-7)
• EPA Substance Registry System: 1-(TRIMETHYLSILYL)PIPERIDINE(3768-56-7)

Safety Data

• Statements: R10:Flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S36:Wear suitable prot
• Hazardous Substances Data: 3768-56-7(Hazardous Substances Data)

Usage

Uses

N-PiperidinoTrimethylsilane has been used in the synthesis of novel hydroborating agents.

InChI:InChI=1/C8H19NSi/c1-10(2,3)9-7-5-4-6-8-9/h4-8H2,1-3H3

Upstream product

• 27325-49-1 1-piperidinylphosphorous dichloride 
• 75-77-4 chloro-trimethyl-silane 
• 110-89-4 piperidine 
• 333361-87-8 bis(trimethylsilyl) [2-(2-furyl)-1-(trimethylsilyloxycarbonyl)ethyl]phosphonite 
• 333364-16-2 bis(trimethylsilyl) 2-(2-furyl)ethylphosphonite 

Downstream Products

• 107-46-0 Hexamethyldisiloxane 
• 33402-83-4 dipiperidinomethyl-2 furanne 
• 33402-89-0 α,α-bis(piperidyl)-4-methoxytoluene 
• 164653-04-7 2-(Piperidinocarbonylamino)benzoylguanidine 
• 164653-03-6 5-Chloro-2-(piperidinocarbonylamino)benzoylguanidine 
• 110-89-4 piperidine 
• 100632-34-6 N-benzoyl-N'-(piperidine-1-carbonyl)-hydrazine 
• 122713-66-0 piperidino-3 phenyl-2 (pyridyl-3)-3 propionate de methyle 
• 122713-65-9 piperidino-3 phenyl-2 (pyridyl-2)-3 propionate de methyle 
• 6278-04-2 1-[phenyl(piperidin-1-yl)methyl]naphthalen-2-ol 
• 70243-82-2 phenyl-(2-(piperidin-1-yl)-phenyl)-methanol 
• 2170-06-1 1-Phenyl-2-(trimethylsilyl)acetylene 
• 93175-51-0 1-((E)-1,3-Diphenyl-3-trimethylsilanyloxy-allyl)-piperidine 
• 93516-09-7 3-phenyl-1,3-dipiperidino-propene 

Relevant articles and documents

Preparation, Characterization, and Reactivity of Aliphatic Amino Iodane(III) Reagents

The preparation of a new class of aliphatic amino iodane(III) reagents has been realized with the N-TMS?amine and acetoxybenziodazole participated in the formation of N?I bond. The amino-containing iodane(III) reagent 2 d was characterized by single-crystal X-ray diffraction, which revealed the expected hypervalent iodane distorted T-shaped geometry. A practical copper-catalyzed, directed electrophilic amination of aryl amines employing amino-iodane(III) as amination agents was disclosed that proceeded smoothly without external additives.

Three-component coupling of arynes, aminosilanes, and aldehydes

A three-component coupling of arynes, aminosilanes, and aldehydes enables diverse amino and hydroxymethyl groups to be incorporated directly into 1,2-positions of aromatic rings.

Addition of bis(trimethylsiloxy)phosphine to 2-vinylfuran

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