380-57-4

Basic information

• Product Name: 1,4-DIBROMO-2-CHLORO-1,1,2-TRIFLUOROPENTANE
• Synonyms: 1,4-DIBROMO-2-CHLORO-1,1,2-TRIFLUOROPENTANE;2-CHLORO-1,4-DIBROMO-1,1,2-TRIFLUOROPENTANE
• CAS NO: 380-57-4
• Molecular Formula: C5H6Br2ClF3
• Molecular Weight: 318.36
• Mol File: 380-57-4.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 66°C 11mm
• Flash Point: 66°C
• Appearance: /
• Density: 1.922g/cm³
• CAS DataBase Reference: 1,4-DIBROMO-2-CHLORO-1,1,2-TRIFLUOROPENTANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-DIBROMO-2-CHLORO-1,1,2-TRIFLUOROPENTANE(380-57-4)
• EPA Substance Registry System: 1,4-DIBROMO-2-CHLORO-1,1,2-TRIFLUOROPENTANE(380-57-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 380-57-4(Hazardous Substances Data)

Usage

General Description

1,4-Dibromo-2-chloro-1,1,2-trifluoropentane is a chemical compound with the molecular formula C5H7Br2ClF3. It is a colorless, volatile liquid that is primarily used as a refrigerant and a blowing agent in the production of foam insulation. 1,4-DIBROMO-2-CHLORO-1,1,2-TRIFLUOROPENTANE is also used in the manufacture of pharmaceuticals and agrochemicals. 1,4-Dibromo-2-chloro-1,1,2-trifluoropentane is known to be harmful if inhaled or ingested, and it can cause irritation to the skin and eyes. It is important to handle this compound with care and follow proper safety guidelines when working with it.

Upstream product

• 187737-37-7 propene 
• 354-51-8 1,2-dibromo-1-chloro-1,2,2-trifluoroethane 
• 94-36-0 dibenzoyl peroxide 

Downstream Products

• 356-73-0 1,1,2-Trifluor-2-chlor-1-brom-penten-(3) 

Relevant articles and documents

1-Vinyl-1,2,2,3,3-pentafluorocyclopropane: An extraordinarily rapid vinylcyclopropane rearrangement

The synthesis of 1-vinyl-1,2,2,3,3-pentafluorocyclopropane (1) and the kinetics of its thermal, unimolecular rearrangement to 1,4,4,5,5-pentafluorocyclopentene (2) are reported. Kinetic data were obtained by gas-phase 19FNMR at 80-120 °C, and the activation parameters for the rearrangement of 1 to 2 are: ΔG?(100 °C) = 28.7 kcal/mol, ΔH? = 26.7 kcal/mol, and ΔS? = -5.5 eu (log A = 12.7, Ea = 28.4 kcal/mol). Vinyl(pentafluorocyclopropane) (1) with a half-life of only 38 min at 110 °C, is one of the most thermally labile vinylcyclopropanes known. The isomeric E- and Z-1-propenyl-1,2,2,3,3-pentafluorocyclopropanes (3) similarly have relatively low activation parameters: ΔG?(E) ? 28.5 kcal/mol and ΔG?(Z) ? 31.1 kcal/mol. A favorable, polar biradical transition state for rearrangement is proposed to account the exceptional reactivity of these alkenyl pentafluorocyclopropanes.