38018-60-9

Basic information

• Product Name: Benzenamine, N-[(2-bromophenyl)methylene]-4-methoxy-
• CAS NO: 38018-60-9
• Molecular Formula: C14H12BrNO
• Molecular Weight: 290.159
• Mol File: 38018-60-9.mol
• Article Data: 28

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-[(2-bromophenyl)methylene]-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-[(2-bromophenyl)methylene]-4-methoxy-(38018-60-9)
• EPA Substance Registry System: Benzenamine, N-[(2-bromophenyl)methylene]-4-methoxy-(38018-60-9)

Safety Data

• Hazardous Substances Data: 38018-60-9(Hazardous Substances Data)

Upstream product

• 104-94-9 4-methoxy-aniline 
• 6630-33-7 ortho-bromobenzaldehyde 
• 18982-54-2 o-bromobenzyl alcohol 

Downstream Products

• 757977-14-3 (3R,4S)-1-benzoyl-3-O-triisopropylsilyloxy-4-(o-allylphenyl)azetidin-2-one 
• 941672-61-3 4-(2-bromo-phenyl)-3-hydroxy-1-(4-methoxy-phenyl)-azetidin-2-one 
• 930785-90-3 3-triisopropylsilanyloxy-4-(2-vinyl-phenyl)-azetidin-2-one 
• 757977-12-1 4-(2-allyl-phenyl)-3-triisopropylsilanyloxy-azetidin-2-one 
• 860782-81-6 4-(2-bromo-phenyl)-1-(4-methoxy-phenyl)-3-triisopropylsilanyloxy-azetidin-2-one 
• 860782-60-1 (3R,4S)-1-benzoyl-3-O-triisopropylsilyloxy-4-(o-vinylphenyl)azetidin-2-one 
• 860782-58-7 1-(4-methoxy-phenyl)-3-triisopropylsilanyloxy-4-(2-vinyl-phenyl)-azetidin-2-one 
• 860782-59-8 4-(2-allyl-phenyl)-1-(4-methoxy-phenyl)-3-triisopropylsilanyloxy-azetidin-2-one 
• 860782-80-5 C₄₉H₅₁NO₁₄ 
• 757977-17-6 C₄₉H₅₁NO₁₄ 
• 930785-79-8 C₅₀H₅₃NO₁₅ 
• 930785-81-2 C₅₀H₅₃NO₁₅ 
• 860782-79-2 C₆₄H₈₅NO₁₄Si₂ 
• 860782-64-5 3'-dephenyl-3'-(o-vinylphenyl)-4-deacetyl-4-acryloyl-7-O-triethylsilyl-2'-O-triisopropylsilylpaclitaxel 

Relevant articles and documents

Arene diruthenium(II)-mediated synthesis of imines from alcohols and amines under aerobic condition

The utility and selectivity of the newly synthesized dinuclear arene Ru(II) complex were demonstrated towards the synthesis of imines from coupling of alcohols and amines in the aerobic condition. Analytical and various spectral methods have been used to establish the unprecedented formation of the new thiolato-bridged dinuclear ruthenium complex. The molecular structure of the titled complex was evidenced with aid of X-ray crystallographic technique. A wide range of imines were obtained in good-to-excellent yields up to 98% and water as the by-product through an acceptorless dehydrogenative coupling of alcohols with amines. The catalytic reaction operated a concise atom economical without any oxidant with 1 mol% of the catalyst load. Further, the role of base, solvent and catalyst loading of the coupling reaction has been investigated. A plausible mechanism has been described and was found to proceed via the formation of an aldehyde intermediate. Short synthesis of antibacterial drug N-(salicylidene)-2-hydroxyaniline illustrated the utility of the present protocol.

Manganese-Catalyzed Electrochemical Tandem Azidation-Coarctate Reaction: Easy Access to 2-Azo-benzonitriles

A one-pot cascade transformation consisting of an electrochemically driven azidation of 2H-indazole followed by coarctate fragmentation is developed to synthesize the 2-azo-benzonitrile motif. This manganese-catalyzed transformation is external-chemical-oxidant-free and operates at ambient temperature under air. This methodology exhibits good functional group tolerance, affording a broad range of substrate scopes of up to 89% isolated yield. Diverse derivatization of the 2-azo-benzonitrile product resulted in other valuable scaffolds.

Enantioselective Direct anti-Selective Mannich-type Reactions Catalyzed by 3-Pyrrolidinecarboxylic Acid in the Presence of Potassium Carbonate: Addition of Potassium Carbonate Improves Enantioselectivities

Mannich-type reactions of cyclohexanone and related six-membered-ring ketones with N-p-methoxyphenyl-protected imines of arylaldehydes catalyzed by 3-pyrrolidinecarboxylic acid in the presence of K2CO3 that afford anti-isomers of the Mannich products with