38031-97-9Relevant articles and documents
Highly Efficient Aza-Michael Reactions of Enones with Carbamates Using a Combination of Quaternary Ammonium Salts and BF3·OEt 2 as a Catalyst
Xu, Li-Wen,Li, Lyi,Xia, Chun-Gu,Zhou, Shao-Lin,Li, Jing-Wei,Hu, Xiao-Xue
, p. 2337 - 2340 (2003)
Aza-Michael reactions of enones with carbamates took efficiently in the presence of a catalytic amount of quaternary ammonium salts and BF 3·OEt2 to afford the total products in high yields. The new catalytic system was also efficient in the aza-Michael reaction of chalcone, which was difficult to react with carbamates by transition metal salts catalysts.
Acidic-functionalized ionic liquid as an efficient, green and reusable catalyst for hetero-Michael addition of nitrogen, sulfur and oxygen nucleophiles to α,β-unsaturated ketones
Han, Feng,Yang, Lei,Li, Zhen,Xia, Chungu
experimental part, p. 346 - 354 (2012/01/14)
A series of acidic-functionalized ionic liquids were synthesized and applied to the hetero-Michael addition of nitrogen, sulfur and oxygen nucleophiles to α,β-unsaturated ketones under solvent-free conditions. Notably, 1-methylimidazolium p-toluenesulfoni
Highly efficient phosphine-catalyzed aza-Michael reactions of α,β-unsaturated compounds with carbamates in the presence of TMSCl
Xu, Li-Wen,Xia, Chun-Gu
, p. 4507 - 4510 (2007/10/03)
Aza-Michael reactions of enones with carbamates took place efficiently in the presence of a catalytic amount of phosphine and TMSCl to afford the total products in high yields. The new catalytic system was also efficient in the aza-Michael reaction of chalcone, which was difficult to react with carbamates by transition metal salts catalysts.