38089-02-0

Basic information

• Product Name: 3'-METHOXYBIPHENYL-2-YLAMINE
• Synonyms: AKOS BAR-0099;AKOS B025032;3'-METHOXYBIPHENYL-2-YLAMINE;3'-METHOXY[1,1'-BIPHENYL]-2-AMINE;CHEMBRDG-BB 4002082;ART-CHEM-BB B025032;TIMTEC-BB SBB007488;(3'-methoxybiphenyl-2-yl)amine(SALTDATA: HCl)
• CAS NO: 38089-02-0
• Molecular Formula: C₁₃H₁₃NO
• Molecular Weight: 199.25
• Mol File: 38089-02-0.mol
• Article Data: 42

Chemical Properties

• Boiling Point: 337.5±17.0 °C(Predicted)
• Appearance: /
• Density: 1.100±0.06 g/cm3(Predicted)
• PKA: 3.66±0.10(Predicted)
• CAS DataBase Reference: 3'-METHOXYBIPHENYL-2-YLAMINE(CAS DataBase Reference)
• NIST Chemistry Reference: 3'-METHOXYBIPHENYL-2-YLAMINE(38089-02-0)
• EPA Substance Registry System: 3'-METHOXYBIPHENYL-2-YLAMINE(38089-02-0)

Safety Data

• Hazardous Substances Data: 38089-02-0(Hazardous Substances Data)

Upstream product

• 2398-37-0 3-methoxyphenyl bromide 
• 191171-55-8 2-anilineboronic acid pinacol ester 
• 10365-98-7 3-methoxyphenylboronic acid 
• 62-53-3 aniline 
• 4471-22-1 Phenyl-trityl-amine 
• 556812-41-0 4-methoxy-2-(trimethylsilyl)phenyl triflate 
• 615-43-0 2-iodophenylamine 
• 615-36-1 2-bromoaniline 
• 88-73-3 2-Chloronitrobenzene 
• 100-66-3 methoxybenzene 
• 92017-95-3 2-(3-Methoxyphenyl)nitrobenzene 

Downstream Products

• 1412912-57-2 C₂₀H₁₄BrNO 
• 41001-28-9 9-methoxyphenanthridine 
• 1194718-79-0 7-methoxyphenanthridine 
• 18992-85-3 3-methoxycarbazole 
• 4544-87-0 1-methoxy-9H-carbazole 
• 1565834-82-3 2-((((3'-methoxy-[1,1'-biphenyl]-2-yl)imino)methylene)amino)benzonitrile 
• 1448169-48-9 (E)-2'-(1,2-diphenylethenyl)-5'-methoxy[1,1'-biphenyl]-2-amine 
• 1426813-06-0 9-methoxy-5-(phenylsulfonyl)phenanthridin-6(5H)-one 
• 1426813-05-9 9-methoxy-5-tosylphenanthridin-6(5H)-one 
• 1423075-13-1 N-(2-pyridyl)sulfonyl 2-amino-3'-methoxybiphenyl 

Relevant articles and documents

Modular Tandem Mizoroki-Heck/Reductive Heck Reactions to Construct Fluorenes from Cyclic Diaryliodoniums

Starting from cyclic diaryliodoniums and terminal alkenes, a diverse set of fluorenes is conveniently constructed. The reactions catalyzed by palladium undergo one conventional Mizoroki-Heck reaction and one reductive Heck reaction. The scope of alkenes is general, leading to 29 fluorenes which would expand the structural diversity of fluorene reservoir. (Figure presented.).

Catalytic Synthesis of Dibenzazepines and Dibenzazocines by 7-Exo- and 8-Endo-Dig-Selective Cycloisomerization

The 7-exo- and 8-endo-dig-selective gold-catalyzed cycloisomerizations of 2-propargylamino biphenyl derivatives were developed. The reaction of terminal alkynes gave dibenzo[b,d]azepines by 7-exo-dig cycloisomerization. In contrast, when internal alkynes were subjected to the reaction, 8-endo-dig cycloisomerization proceeded to provide dibenzo[b,d]azocines. The nucleophilicity at the reaction site and the electron-withdrawing effect of a tosyl group were important for the present selective transformation. This protocol could be used for ynamide substrates and a silver-catalyzed reaction gave 7-exo-dig products selectively.

Photocatalytic xanthate-based radical addition/cyclization reaction sequence toward 2-biphenyl isocyanides: Synthesis of 6-alkylated phenanthridines

A photocatalytic xanthate-based radical addition/cyclization reaction cascade toward 2-biphenylisocyanides is described as a practical and modular approach to 6-alkylated phenanthridines. The use of xanthates as radical precursors allowed the synthesis of diversely 6-substituted phenanthridines. Electrophilic radicals derived from nitriles, aromatic and aliphatic ketones, malonates, and amide derivatives, as well as radicals derived from phthalimidomethyl and benzylic derivatives were successfully introduced. The reaction proceeds under mild conditions without a stoichiometric amount of oxidant. Thirty novel phenanthridine scaffolds were synthesized with yields ranging from 24 to 76%.