381218-96-8

Basic information

• Product Name: Boronic acid, (4-[2,2':6',2''-terpyridin]-4'-ylphenyl)-
• CAS NO: 381218-96-8
• Molecular Formula: C21H16BN3O2
• Molecular Weight: 353.188
• Mol File: 381218-96-8.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Boronic acid, (4-[2,2':6',2''-terpyridin]-4'-ylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Boronic acid, (4-[2,2':6',2''-terpyridin]-4'-ylphenyl)-(381218-96-8)
• EPA Substance Registry System: Boronic acid, (4-[2,2':6',2''-terpyridin]-4'-ylphenyl)-(381218-96-8)

Safety Data

• Hazardous Substances Data: 381218-96-8(Hazardous Substances Data)

Upstream product

• 1122-62-9 2-acetylpyridine 
• 76-09-5 2,3-dimethyl-2,3-butane diol 
• 87199-17-5 4-formylphenylboronic acid, 
• 10602-01-4 p-bromobenzaldehyde 1,3-dioxolane 
• 1122-91-4 4-bromo-benzaldehyde 
• 89972-76-9 4'-(4-bromo-phenyl)-[2,2';6',2'']terpyridine 
• 381218-92-4 4'-[4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)phenyl]-2,2':6',2''-terpyridine 

Downstream Products

• 1219501-45-7 4-(7,8,13,14-tetrahydroquino[8,7-k][1,8]phenanthrolin-6-yl)-4'([2,2';6',2'']terpyridin-4'-yl)biphenyl 
• 1219501-43-5 4-(5,6,8,9-tetrahydroquino[8,7-b][1,10]phenanthrolin-7-yl)-4'([2,2';6',2'']terpyridin-4'-yl)biphenyl 

Relevant articles and documents

Photocatalytic atom transfer radical addition to olefins utilizing novel photocatalysts

Photocatalysis is a rapidly evolving area of research in modern organic synthesis. Among the traditional photocatalysts, metal-complexes based on ruthenium or iridium are the most common. Herein, we present the synthesis of two photoactive, ruthenium-based complexes bearing pyridine-quinoline or terpyridine ligands with extended aromatic conjugation. Our complexes were utilized in the atom transfer radical addition (ATRA) of haloalkanes to olefins, using bromoacetonitrile or bromotrichloromethane as the source of the alkyl group. The tailor-made ruthenium-based catalyst bearing the pyridine-quinoline bidentate ligand proved to be the best-performing photocatalyst, among a range of metal complexes and organocatalysts, efficiently catalyzing both reactions. These photocatalytic atom transfer protocols can be expanded into a broad scope of olefins. In both protocols, the photocatalytic reactions led to products in good to excellent isolated yields.

Detection of Picric Acid by Terpy-Based Metallo-Supramolecular Fluorescent Coordination Polymers in Aqueous Media

The synthesis of two linear terpy-based metallo-supramolecular fluorescent coordination polymers through 1∶1 complexation of Zn2+ and Cd2+ ions with ditopic terpyridine ligand was reported. The dispersibility of P1 and P2 was significantly improved in organic solvent and water through the introduction of hydrophilic oligo-ethyoxy side chain. Two polymers displayed yellow light emission both in solution and the solid state due to the intra-ligand charge transfer (ILCT) between the d10 metal ions and the conjugated spacer unit. These coordination polymers were explored as fluorescent chemosensors for detecting picric acid in aqueous media, displaying high sensitivity and good selectivity. In addition, test strips were prepared from these polymers and exhibited the practical potential of detecting the NACs pollutants in the outdoor water for public safety and security.

Tunable Luminescent Lanthanide Supramolecular Assembly Based on Photoreaction of Anthracene

Lanthanide luminescence materials generally show great superiority in light-emitting materials, gaining increasingly exploration in the design of advanced functional materials. Herein, we prepared a supramolecular assembly via the coordination of a host m