381227-08-3Relevant articles and documents
O,N-bidentate ruthenium azo complexes as catalysts for olefin isomerization reactions
Ding, Fu,Sun, Yaguang,Verpoort, Francis
, p. 1536 - 1543 (2010/07/16)
A series of ruthenium complexes [(η6-p-cymene) RuCl(L)] [ligands L incorporate an azo group (1-5) or an imino group (67)] havo boon synthesized and studied as olefin isomerization catalyst with allylbenzene and 1-octene as model substrates. Temperature and catalyst/substrate mol ratio have been taken into account as parameters to optimize the isomerization reaction conditions. By using 1H, 13C NMR, FT-JR and microanalysis, the new complexes have been characterized and the molecular structure of complex 4 has been determined by crystal structure determination.