38184-15-5

Basic information

• Product Name: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl-(1<*>6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside
• Synonyms: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl-(1<*>6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside
• CAS NO: 38184-15-5
• Molecular Weight: 939.112
• Mol File: 38184-15-5.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl-(1<*>6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl-(1<*>6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside(38184-15-5)
• EPA Substance Registry System: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl-(1<*>6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside(38184-15-5)

Safety Data

• Hazardous Substances Data: 38184-15-5(Hazardous Substances Data)

Upstream product

• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 4356-77-8 1,6-di-O-acetyl-2,3,4-tri-O-benzyl-D-glucopyranose 
• 35094-58-7 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl bromide 
• 787623-80-7 p-methylphenyl 6-O-acetyl-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside 
• 479252-05-6 ((2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-p-tolylsulfanyl-tetrahydro-pyran-2-yl)-methanol 
• 88567-49-1 6-O-acetyl-2,3,4-tri-O-benzyl-D-glucopyranose 

Downstream Products

• 145149-86-6 O-(6-O-Acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1->6)-1-O-acetyl-2,3,4-tri-O-benzyl-α,β-D-glucopyranose 
• 116730-84-8 Methyl O-(2,3,4-tri-O-benzyl-6-deoxy-6-fluoro-α-D-glucopyranosyl)-(1-6)-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1-6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 116730-86-0 Methyl O-(2,3,4-tri-O-benzyl-6-deoxy-6-fluoro-β-D-glucopyranosyl)-(1-6)-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1-6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 116730-79-1 Methyl O-(2,3,4-tri-O-benzyl-6-deoxy-6-fluoro-α-D-glucopyranosyl)-(1-6)-tri-O-benzyl-α-D-glucopyranoside 
• 110383-80-7 Trimethyl-[(2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-ylmethoxy]-silane 
• 116730-82-6 Methyl O-(2,3,4-tri-O-benzyl-6-deoxy-6-fluoro-β-D-glucopyranosyl)-(1-6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 53810-61-0 methyl 2,3,4-tri-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 

Relevant articles and documents

A "traceless" Directing Group Enables Catalytic SN2 Glycosylation toward 1,2- cis-Glycopyranosides

Generally applicable and stereoselective formation of 1,2-cis-glycopyranosidic linkage remains a long sought after yet unmet goal in carbohydrate chemistry. This work advances a strategy to this challenge via stereoinversion at the anomeric position of 1,2-trans glycosyl ester donors. This SN2 glycosylation is enabled under gold catalysis by an oxazole-based directing group optimally tethered to a leaving group and achieved under mild catalytic conditions, in mostly excellent yields, and with good to outstanding selectivities. The strategy is also applied to the synthesis of oligosaccharides.

HEPARANASE INHIBITORS AND THEIR USE AS ANTI-CANCER COMPOUNDS

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A flexible 1,2-cis α-glycosylation strategy based on in situ adduct transformation

A flexible 1,2-cis α-selective glycosylation strategy for a wide range of glycosyl donors and acceptors has been developed, which is based on an in situ adduct transformation protocol. Based on this strategy, both NFM-derived and iodide covalent adducts c