382-24-1Relevant articles and documents
CONDENSATION OF PERFLUOROISOBUTYLENE WITH ACETONITRILE
Postovoi, S. A.,Zeifman, Yu. V.
, p. 197 - 198 (1982)
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The reactivities of perfluoroisopropyl and tert-butyl radicals towards hydrogen atom abstraction from triethylsilane
Dolbier Jr., William R.,Li, An-Rong
, p. 79 - 82 (2007/10/03)
The rates of hydrogen abstraction from triethylsilane by the highly electrophilic perfluoroisopropyl and perfluoro-tert-butyl radicals have been obtained through competition experiments. These rates, 3.6 × 106 and 2.4 × 108 M-1 s-1, respectively, are indicative of substantial reactivity enhancements, relative to perfluoro-n-alkyl radicals, derived from their enhanced electrophilicity and, in the latter case, from a much stronger forming C-H bond.
Interaction of 1-tert-perfluorobutyl-3,3-di(perfluoromethyl)-2-aziridinone with weak nucleophiles
Del'tsova, D. I.,Gambaryan, N. P.
, p. 333 - 336 (2007/10/02)
The title perfluoro-α-lactam (1) was found to react with N,N-dimethylformamide to give initially a betaine (2) which undergoes ring enlargement to produce the isomeric 2-dimethylamino-3,4,4-tri(perfluoroalkyl)substituted 5-oxazolidone (3).Related betaines were also obtained on reaction of 1 with pyridine, quinoline, benzalaniline, and p-dimethylaminobenzaldehyde.
FLUORINE-CONTAINING IMINES. COMMUNICATION 6. REACTION OF HEXAFLUOROACETONE PERFLUOROPIVALOYLIMINE WITH DIMETHYLANILINE AND DIMETHYLBENZYLAMINE
Gambaryan, N. P.,Del'tsova, D. P.,Safronova, Z. V.,Kaitmazova, G. S.
, p. 1873 - 1875 (2007/10/02)
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