38257-96-4Relevant articles and documents
A new class of organogelators based on triphenylmethyl derivatives of primary alcohols: Hydrophobic interactions alone can mediate gelation
Singh, Wangkhem P.,Singh, Rajkumar S.
supporting information, p. 138 - 149 (2017/02/15)
In the present work, we have explored the use of the triphenylmethyl group, a commonly used protecting group for primary alcohols as a gelling structural component in the design of molecular gelators. We synthesized a small library of triphenylmethyl deri
Elaboration of the ether cleaving ability and selectivity of the classical Pearlman's catalyst [Pd(OH)2/C]: Concise synthesis of a precursor for a myo-inositol pyrophosphate
Mart, Alson,Shashidhar, Mysore S.
, p. 9769 - 9776,8 (2012/12/11)
The cleavage of propargyl, allyl, benzyl, and PMB ethers by Pd(OH) 2/C can be tuned in that order, by varying the reaction conditions. Other moieties such as C-C double bonds, esters, trityl ether, p-bromo and p-nitrobenzyl ethers are stable to these reaction conditions. Cleavage of allyl ethers can be made catalytic by using 1:1 mixture of Pd(OH)2/C and Pd/C. The synthetic potential of the selective ether cleaving ability of Pd(OH)2/C, essentially under neutral conditions, has been demonstrated by an efficient synthesis of a precursor for the preparation of an inositol pyrophosphate derivative.
N1-substituted thymine derivatives as mitochondrial thymidine kinase (TK-2) inhibitors
Hernández, Ana-Isabel,Familiar, Olga,Negri, Ana,Rodríguez-Barrios, Fátima,Gago, Federico,Karlsson, Anna,Camarasa, María-José,Balzarini, Jan,Pérez-Pérez, María-Jesús
, p. 7766 - 7773 (2007/10/03)
Novel N1-substituted thymine derivatives related to 1-[(Z)-4-(triphenylmethoxy)-2-butenyl]thymine have been synthesized and evaluated against thymidine kinase-2 (TK-2) and related nucleoside kinases [i.e., Drosophila melanogaster deoxynucleosid