383-67-5Relevant articles and documents
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Hoffmann,H.M.R. et al.
, p. 2257 - 2261 (1971)
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Ortho-Phenylene bridged palladium bis-N-heterocyclic carbene complexes: Synthesis, structure and catalysis
Munz, Dominik,Poethig, Alexander,Tronnier, Alexander,Strassner, Thomas
, p. 7297 - 7304 (2013/07/11)
A series of ortho-phenylene bridged palladium bis-NHC complexes has been synthesized. Complexes with imidazolium and benzimidazolium derived NHCs and methyl-/benzyl-wingtips are reported. Bis(benz)imidazoles with a doubly brominated ortho-phenylene bridge could be obtained by an electrophilic substitution reaction. The structure of the complexes could be confirmed by three solid-state structures. All catalysts have been tested in the catalytic functionalisation of propane. The catalytic activity is highly dependent on the ligand, whereas ligand effects on the regioselectivity (n/iso) are much smaller.
Synthesis of bicyclo[2.2.1]hept-5-enyl methyl esters of haloacetic acids
Kyazimova,Mamedbeili,Nagiev,Suleimanova,Khalilov
experimental part, p. 1803 - 1807 (2009/09/08)
Synthesis of norbornenyl methyl esters of a number of haloacetic acids via [4+2] cycloaddition of cyclopentadiene to allyl esters of these acids was examined. The yield and isomer composition of the synthesized compounds were examined in relation to the reaction conditions, and the best conditions for their preparation were found.