383176-10-1

Basic information

• Product Name: Benzaldehyde, 5-bromo-2,4-dimethyl-
• CAS NO: 383176-10-1
• Molecular Formula: C9H9BrO
• Molecular Weight: 213.074
• Mol File: 383176-10-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 5-bromo-2,4-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 5-bromo-2,4-dimethyl-(383176-10-1)
• EPA Substance Registry System: Benzaldehyde, 5-bromo-2,4-dimethyl-(383176-10-1)

Safety Data

• Hazardous Substances Data: 383176-10-1(Hazardous Substances Data)

Upstream product

• 824-55-5 2,4-dimethyl-benzyl chloride 
• 36276-24-1 3-bromo-4-methyl-benzaldehyde 
• 15764-16-6 2,4-dimethylbenzaldehyde 
• 615-87-2 1,5-dibromo-2,4-dimethylbenzene 
• 807628-76-8 5-bromo-2,4-dimethylbenzonitrile 
• 854693-48-4 5-bromo-2,4-dimethyl-benzyl chloride 

Downstream Products

• 807628-68-8 5-cyano-2,4-dimethylbenzaldehyde 
• 842136-27-0 5-bromo-2,4-dimethylbenzoic acid 

Relevant articles and documents

Pd-Catalyzed, ortho C-H Methylation and Fluorination of Benzaldehydes Using Orthanilic Acids as Transient Directing Groups

The direct, Pd-catalyzed ortho C-H methylation and fluorination of benzaldehydes have been accomplished using commercially available orthanilic acids as transient directing groups. In these reactions, the 1-fluoro-2,4,6-trimethylpyridinium salts can be either a bystanding F+ oxidant or an electrophilic fluorinating reagent. An X-ray crystal structure of a benzaldehyde ortho C-H palladation intermediate was obtained using triphenylphosphine as the stabilizing ligand.

Highly diastereoselective tandem photoenolization-hetero-Diels-Alder cycloaddition reactions of o-tolualdehydes in the solid state

The (E)-photoenols generated in situ by photolysis of o-tolualdehydes 1-5 in the solid state react with the precursor aldehydes as dienophiles in a hetero-Diels-Alder cycloaddition fashion to afford trans-3-arylisochromanols in excellent yields and in a h