38416-56-7

Basic information

• Product Name: BENZYL 2-ACETAMIDO-3,4,6-TRI-O-BENZYL-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE
• Synonyms: 2-Acetamido-1,3,4,6-tetra-O-benzyl-2-deoxy-a-D-glucopyranoside;PhenylMethyl 2-(AcetylaMino)-2-deoxy-3,4,6-tris-O-(phenylMethyl)-α-D-glucopyranoside
• CAS NO: 38416-56-7
• Molecular Formula: C₃₆H₃₉NO₆
• Molecular Weight: 581.7
• Product Categories: Carbohydrates & Derivatives
• Mol File: 38416-56-7.mol
• Article Data: 7

Chemical Properties

• Melting Point: 167-168°C
• Boiling Point: 737.858 °C at 760 mmHg
• Flash Point: 400.042 °C
• Appearance: /
• Density: 1.208 g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.609
• Storage Temp.: -20°C Freezer
• CAS DataBase Reference: BENZYL 2-ACETAMIDO-3,4,6-TRI-O-BENZYL-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE(CAS DataBase Reference)
• NIST Chemistry Reference: BENZYL 2-ACETAMIDO-3,4,6-TRI-O-BENZYL-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE(38416-56-7)
• EPA Substance Registry System: BENZYL 2-ACETAMIDO-3,4,6-TRI-O-BENZYL-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE(38416-56-7)

Safety Data

• Hazardous Substances Data: 38416-56-7(Hazardous Substances Data)

Usage

Chemical Properties

White to Off-White Powder

InChI:InChI=1/C36H39NO6/c1-27(38)37-33-35(41-24-30-18-10-4-11-19-30)34(40-23-29-16-8-3-9-17-29)32(26-39-22-28-14-6-2-7-15-28)43-36(33)42-25-31-20-12-5-13-21-31/h2-21,32-36H,22-26H2,1H3,(H,37,38)/t32?,33-,34+,35+,36-/m0/s1

Upstream product

• 7512-17-6 N-Acetyl-D-glucosamine 
• 108-24-7 acetic anhydride 
• 100-39-0 benzyl bromide 
• 4171-73-7 2-acetamido-1-O-acetyl-2-deoxy-3,4,6-tri-O-benzyl-α-D-glucopyranose 
• 100-51-6 benzyl alcohol 
• 67398-54-3 benzyl 2-acetamido-3-O-benzyl-2-deoxy-4,6-O-isopropylidene-α-D-glucopyranoside 
• 14146-26-0 benzyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 14146-27-1 benzyl 3-O-benzyl-2-acetamido-2-deoxy-α-D-glucopyranoside 
• 100-44-7 benzyl chloride 
• 13343-63-0 benzyl 4,6-O-benzylidene-2-acetylamino-2-deoxy-α-D-glucopyranoside 
• 66026-10-6 N-((4aR,6S,7R,8R,8aS)-6-(benzyloxy)-8-hydroxy-2,2-dimethylhexahydropyrano[3,2-d][1,3]dioxin-7-yl)acetamide 

Relevant articles and documents

Formation of 2-acetamido-2-deoxy-d-glucopyranosidic linkages via glycosidation using a combination of two lewis acids

A mixed activation system composed of ytterbium(III) triflate and a catalytic boron trifluoride diethyl etherate complex efficiently promotes the glycosylation of various alcohol acceptors using 2-acetamido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl ac

Order of reactivity of OH/NH groups of glucosamine hydrochloride and N -Acetyl glucosamine toward benzylation using NaH/BnBr in DMF

The order of reactivity of OH and NH groups of glucosamine hydrochloride (GlcNH2HCl) and N-acetyl glucosamine (GlcNAc) toward benzylation with NaH/BnBr in DMF was investigated. For GlcNH2.HCl, benzyl groups were introduced in the order of N-Bn > N-Bn2 > 1-O-Bn > 6-O-Bn > 4-O-Bn > 3-O-Bn; for GlcNAc, benzyl groups were introduced in the order of 1-O-Bn > 6-O-Bn > 4-O-Bn > 3-O-Bn > N-Bn. A range of partially benzylated 2-N,N′-dibenzyl glucopyranosides and GlcNAc derivatives were obtained in a single step. Taylor & Francis Group, LLC.

APPROACHES TO THE SELECTIVE BENZYLATION OF THE PRIMARY HYDROXYL GROUP

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