38465-86-0 Usage
Description
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE, also known as [Ir(cod)(PPh2Me)2]PF6, is an air-stable cationic iridium complex that exists as a red crystalline powder. It is characterized by its unique chemical properties and is widely recognized for its role in various chemical reactions, particularly in the field of organic chemistry.
Uses
Used in Chemical Synthesis:
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE is used as a catalyst in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters. This application is significant because it allows for the efficient conversion of starting materials into valuable intermediates, which can be further utilized in the synthesis of complex organic molecules.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE is used as a catalyst for the isomerization of diallyl ethers to allyl (E)-vinyl ethers. This transformation is crucial in the synthesis of various pharmaceutical compounds, as it enables the production of key building blocks with high selectivity and efficiency.
Used in Material Science:
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE is also employed in the isomerization of 1-alkenylboronates to corresponding 3-alkoxyallylboronates. This reaction is essential in the development of new materials with unique properties, such as advanced polymers and specialty chemicals, which can be used in various applications, including electronics, coatings, and adhesives.
Overall, (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE is a versatile and valuable compound in the fields of chemical synthesis, pharmaceuticals, and material science, thanks to its ability to act as an efficient catalyst in various isomerization reactions.
Check Digit Verification of cas no
The CAS Registry Mumber 38465-86-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,8,4,6 and 5 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 38465-86:
(7*3)+(6*8)+(5*4)+(4*6)+(3*5)+(2*8)+(1*6)=150
150 % 10 = 0
So 38465-86-0 is a valid CAS Registry Number.
InChI:InChI=1/2C13H13P.C8H12.2CH3.F5P.FH.Ir/c2*1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;1-2-4-6-8-7-5-3-1;;;1-6(2,3,4)5;;/h2*2-11H,1H3;1-2,7-8H,3-6H2;2*1H3;;1H;/q;;;;;;;-1/p+1/b;;2-1-,8-7-;;;;;/rC28H34IrP2.C8H12.F5P.FH/c1-29(2,30(3,25-17-9-5-10-18-25)26-19-11-6-12-20-26)31(4,27-21-13-7-14-22-27)28-23-15-8-16-24-28;1-2-4-6-8-7-5-3-1;1-6(2,3,4)5;/h5-24,30-31H,1-4H3;1-2,7-8H,3-6H2;;1H/q+1;;;/p-1/b;2-1-,8-7-;;
