386-23-2

Basic information

• Product Name: 9-[4-(trifluoromethyl)phenyl]anthracene
• CAS NO: 386-23-2
• Molecular Formula: C₂₁H₁₃F₃
• Molecular Weight: 322.3231
• Mol File: 386-23-2.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 401°C at 760 mmHg
• Flash Point: 164.7°C
• Density: 1.256g/cm³
• Vapor Pressure: 2.82E-06mmHg at 25°C
• Refractive Index: 1.632
• CAS DataBase Reference: 9-[4-(trifluoromethyl)phenyl]anthracene(CAS DataBase Reference)
• NIST Chemistry Reference: 9-[4-(trifluoromethyl)phenyl]anthracene(386-23-2)
• EPA Substance Registry System: 9-[4-(trifluoromethyl)phenyl]anthracene(386-23-2)

Safety Data

• Hazardous Substances Data: 386-23-2(Hazardous Substances Data)

Upstream product

• 402-43-7 p-trifluoromethylphenyl bromide 
• 100622-34-2 anthracene-9-boronic acid 
• 128796-39-4 4-trifluoromethylphenylboronic acid 
• 1564-64-3 9-Bromoanthracene 
• 441-36-1 2-benzyl-4'-trifluoromethyl-benzophenone 
• 10035-10-6 hydrogen bromide 
• 64-19-7 acetic acid 
• 280-57-9 1,4-diaza-bicyclo[2.2.2]octane 

Relevant articles and documents

When Anthracene and Quinone Avoid Cycloaddition: Acid-Catalyzed Redox Neutral Functionalization of Anthracene to Aryl Ethers

Benzoquinone and 9-phenylanthracene barely undergo anticipated cycloaddition under acid catalysis. Instead, 9-anthracenyl aryl ethers are obtained as unexpected products. Mechanistic studies indicate that the reaction likely undergoes an ionic mechanism between protonated anthracene species and nucleophilic oxygen of 1,4-benzoquinone or 1,4-hydroquinone. A variety of 9-anthracenyl aryl ethers are constructed with this method. Produced anthracenyl aryl ethers are potential scaffolds for new fluorescent molecules.

Substituted aromatic compound, a blue light-emitting materials, the organic EL element

PROBLEM TO BE SOLVED: To provide a substituted aromatic compound, a blue light-emitting material using the same and having high color reproducibility, high color purity and high efficiency, and an organic electroluminescent (EL) element.SOLUTION: The substituted aromatic compound is represented by the general formula [1], where Rto Rare each independently hydrogen or a C1-C4 linear or branched alkyl group; A is hydrogen, a C1-C4 linear or branched alkyl group, or a C1-C4 linear or branched alkoxy group; and EWG is a cyano group or a trifluoromethyl group.

Suzuki-Miyaura cross-coupling of bulky anthracenyl carboxylates by using pincer nickel N-heterocyclic carbene complexes: An efficient protocol to access fluorescent anthracene derivatives

A series of fluorescent (hetero)-aryl substituted anthracene derivatives were readily accessible from the corresponding bulky anthracen-9-yl carboxylates via Suzuki-Miyaura cross-coupling reactions by using pincer nickel N-heterocyclic carbene complex 1 even at the catalyst loading as low as 0.1 mol% in the presence of catalytic amounts of PCy3.