3860-58-0

Basic information

• Product Name: Phenol, 2-[(2-pyridinylmethylene)amino]-
• CAS NO: 3860-58-0
• Molecular Formula: C12H10N2O
• Molecular Weight: 198.224
• Mol File: 3860-58-0.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Phenol, 2-[(2-pyridinylmethylene)amino]-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2-[(2-pyridinylmethylene)amino]-(3860-58-0)
• EPA Substance Registry System: Phenol, 2-[(2-pyridinylmethylene)amino]-(3860-58-0)

Safety Data

• Hazardous Substances Data: 3860-58-0(Hazardous Substances Data)

Upstream product

• 1121-60-4 pyridine-2-carbaldehyde 
• 95-55-6 2-amino-phenol 
• 88-75-5 2-hydroxynitrobenzene 

Downstream Products

• 102212-26-0 N-(2-hydroxyphenyl)-N-(2-pyridylmethyl)amine 
• 474358-93-5 [PdCl2(κ2-N,N'-2-((pyridin-2-ylmethylene)aminophenol))] 
• 474358-89-9 Pd(η(2)-[2-[(pyridin-2-ylmethylidene)amino]phenol])Cl(Me) 
• 474359-04-1 Pd(η(2)-[2-[(pyridin-2-ylmethylidene)amino]phenolato])(Cl)(PPh3) 
• 1217501-90-0 (2-NC₅H₄)C(H)N(C₆H₄O-2)(triphenylphosphane)palladium(II) perchlorate 
• 13524-78-2 3,3-dimethyl-2,3-dihydrobenzo[b]furan 

Relevant articles and documents

Nickel(II) complexes with N,N,O-donor Schiff bases. Self-assembly to two-dimensional network via hydrogen bonding

The syntheses, characterization and crystal structures of two mononuclear nickel(II) complexes are described. Reactions of Ni(O2CCH 3)2·4H2O with the Schiff bases derived from 2-pyridinecarbaldehyde and ortho-am

Synthesis, Theoretical Study and Catalytic Application of Oxidometal (Mo or V) Complexes: Unexpected Coordination Due to Ligand Rearrangement through Metal-Mediated C-C Bond Formation

Two novel dioxidomolybdenum(VI) complexes [MoO2L′1] (1) and [MoO2L′2] (2) containing the MoO22+ motif with unexpected coordination motifs due to ligand rearrangement through Mo-mediated int

Modulating In Vitro Photodynamic Activities of Copper(II) Complexes

The photodynamic activities of selected copper(II) complexes [Cu(L1)B]ClO4 (1,2) and [Cu(L2)B]ClO4 (3,4), where L1 = 2-[(pyridin-2-yl)methyleneamino]phenol, L2 = 2-[(pyridin-2-yl)methylenea

Effects of appended hydroxyl groups and ligand chain length on copper coordination and oxidation activity

Treatment of a series of (imino)pyridine ligands bearing appended hydroxyl groups 2-((pyridin-2-ylmethylene)amino)phenol (Hpyph), 2-((pyridin-2-ylmethylene)amino)ethanol (Hpyet), and 3-((pyridin-2-ylmethylene)amino)propanol (Hpypr) with one equiv. of CuCl2·2H2O afforded the corresponding Cu(ii) complexes in low to moderate yields. The crystal structure of (μ-Cl)2[CuCl(κ2-N,N-Hpyet)]2 reveals a symmetric dinuclear structure with the bidentate N,N-coordination mode of (imino)pyridine with no Cu-OH interaction. On the other hand, the dinuclear Cu(ii) complex of the related propyl ligand Hpypr possesses a significantly different crystal structure involving nucleophilic addition of the hydroxyl group to the aldehyde group of 2-pyridinecarboxaldehyde. The Cu complex/Cu0/TEMPO/Na2CO3 (TEMPO = 2,2,6,6-tetramethylpiperidinyl-1-oxyl) catalyst system generally exhibited good activity for aerobic oxidation of benzyl alcohol to benzaldehyde in H2O at room temperature. The dinuclear Cu(ii) complex (μ-Cl)2[CuCl(κ2-N,N-Hpyet)]2 was demonstrated as an effective catalyst toward aerobic oxidation of various benzyl alcohol derivatives, cinnamyl alcohol, and 2-thiophenemethanol.

Biological properties of heterocyclic pyridinylimines and pyridinylhydrazones

This work describes the synthesis and biological properties of a series of 2- and 4-pyridinylimines and pyridinylhydrazones. All compounds were evaluated in vitro against two species of Leishmania. The antioxidant activity and the toxic effect against mur