38696-08-1

Basic information

• Product Name: Acetic acid, trifluoro-, (4-methoxyphenyl)methyl ester
• CAS NO: 38696-08-1
• Molecular Formula: C10H9F3O3
• Molecular Weight: 234.175
• Mol File: 38696-08-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Acetic acid, trifluoro-, (4-methoxyphenyl)methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, trifluoro-, (4-methoxyphenyl)methyl ester(38696-08-1)
• EPA Substance Registry System: Acetic acid, trifluoro-, (4-methoxyphenyl)methyl ester(38696-08-1)

Safety Data

• Hazardous Substances Data: 38696-08-1(Hazardous Substances Data)

Upstream product

• 105-13-5 4-Methoxybenzyl alcohol 
• 407-25-0 trifluoroacetic anhydride 
• 70887-29-5 4-methoxybenzyl iodide 
• 2966-50-9 silver trifluoroacetate 
• 794525-07-8 (4S,1'E,3'E)-(-1'-{[tert-butyl(dimethyl)silyl]oxy}-2'-methyl-1',3'-pentadienyl)-4-isopropyl-1,3-oxazolidin-2-one 

Downstream Products

• 1388792-38-8 (S)-2-(p-methoxybenzyl)-2,5-dihydrofuran 
• 1388792-78-6 C₁₂H₁₄O₂ 
• 1388793-16-5 (S)-3-(p-methoxybenzyl)-1-cycloheptene 
• 120349-79-3 (S)-tert-butyl 2-(4-methoxybenzyl)-2,5-dihydro-1H-pyrrole-1-carboxylate 
• 1388792-73-1 (S)-3-(p-methoxybenzyl)-1-cyclopentene 
• 123-11-5 4-methoxy-benzaldehyde 

Relevant articles and documents

Stereoselective Alkylation of the Vinylketene Silyl N,O-Acetal and Its Application to the Synthesis of Mycocerosic Acid

Stereoselective alkylation of the vinylketene silyl N,O-acetal possessing a chiral auxiliary has been achieved by using activated alkyl halides including allyl iodides, benzyl iodides, and propargyl iodide with Ag(I) ion in the presence of BF3·

Palladium-catalyzed, asymmetric Mizoroki-Heck reaction of benzylic electrophiles using phosphoramidites as chiral ligands

We report herein the first examples of asymmetric Mizoroki-Heck reactions using benzyl electrophiles. A new phosphoramidite was identified to be an effective chiral ligand in the palladium-catalyzed reaction. The reaction is compatible with polar functional groups and can be readily scaled up. Several cyclic olefins worked well as olefin components. Thirty-one examples are included.