38795-86-7

Basic information

• Product Name: [(PhSn)₄S₆]
• CAS NO: 38795-86-7
• Molecular Weight: 975.659
• Mol File: 38795-86-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(PhSn)₄S₆](CAS DataBase Reference)
• NIST Chemistry Reference: [(PhSn)₄S₆](38795-86-7)
• EPA Substance Registry System: [(PhSn)₄S₆](38795-86-7)

Safety Data

• Hazardous Substances Data: 38795-86-7(Hazardous Substances Data)

Upstream product

• 1124-19-2 phenyltin trichloride 
• 12135-77-2 ammonium pentasulfide 

Relevant articles and documents

Thiastannacyclohexanes (R2SnS)3 and -adamantanes (RSn)4S6: Syntheses, Properties, and Structure

Cyclotristannathianes (4) are obtained from R2SnCl2 (1) and Na2S*9H2O or (CH3)3SiSSi(CH3)3.Analogously, hexathiatetrastannaadamantanes are prepared from RSnCl3(2) and the sulfenylating agents mentoined before.The reaction between dimesityltin dichloride (1a) and Na2S*9H2O depending on the reaction conditions yields either the corresponding dithiadistannacyclobutane (3) or cyclotristannathiane 4a.The structure of the cyclostannathianes 3, 4, and 5 are elucidated by determining the intensity ratio of geminal 119Sn-117Sn couplings.Calculated data are confirmed by experimental values.Additional proof is provided by measuring the change of intensity ratio in the 117Sn-NMR spectrum of 4c.X-ray structure determination proved for (C6F5Sn)4S6 (5g) to have the same geometry as in solution.