38905-70-3Relevant articles and documents
Evidence for the Radical Pair Mechanism in 'Insertion' Reactions of Transition Metal Hydrides with Conjugated Dienes
Thomas, Marian J.,Shackleton, Thomas A.,Wright, Steven C.,Gillis, Daniel J.,Colpa, Johannes P.,Baird, Michael C.
, p. 312 - 314 (1986)
The compounds cpFe(CO)2H and HMn(CO)5 (cp = cyclopentadienyl) react with 1,3-dienes to give the 2-enylmetal products of 1,4-addition of the metal hydrides to the dienes; CIDNP studies indicate that the process involves a radical pair mechanism.