3900-13-8Relevant articles and documents
Convenient preparation of long-chain dialkyl phosphates: Synthesis of dialkyl phosphates
Aitken, R. Alan,Collett, Chris J.,Mesher, Shaun T. E.
experimental part, p. 2515 - 2518 (2012/09/05)
Reaction of phosphorus oxychloride with a primary alcohol (1.8 equiv) and triethylamine (1.8 equiv) in toluene, followed by filtration and treatment with steam, gives dialkyl phosphates in good yield and essentially free from trialkyl phosphate contamination. Georg Thieme Verlag Stuttgart · New York.
Synthesis of Trialkyl Phosphates from White Phosphorus
Romakhin,Nikitin
, p. 1023 - 1026 (2007/10/03)
A new method was proposed for preparing trialkyl phosphates directly from white phosphorus by its electrolysis in a mixture of acetonitrile, alcohol, and water with tetraethylammonium iodide as supporting electrolyte. To increase the amount of the product synthesized in the unit volume of the electrolyte solution and the productivity of the process, phosphorus and water are added to the electrolyte in portions, which allows synthesis of up to 1 mol of trialkyl phosphate in 1 1 of the electrolyte solution.
