39055-88-4

Basic information

• Product Name: Methanone, (4-nitrophenyl)-4-pyridinyl-
• Synonyms: 4-(p-nitrobenzoyl)pyridine;4-nitrobenzoylpyridine;(4-nitro-phenyl)-[4]pyridyl ketone;4-(4'-Nitrobenzoyl)pyridine;4-(4-nitrobenzoyl)pyridine;4-p-nitrobenzoylpyridine
• CAS NO: 39055-88-4
• Molecular Formula: C12H8N2O3
• Molecular Weight: 228.207
• Mol File: 39055-88-4.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Methanone, (4-nitrophenyl)-4-pyridinyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, (4-nitrophenyl)-4-pyridinyl-(39055-88-4)
• EPA Substance Registry System: Methanone, (4-nitrophenyl)-4-pyridinyl-(39055-88-4)

Safety Data

• Hazardous Substances Data: 39055-88-4(Hazardous Substances Data)

Upstream product

• 4329-73-1 N-(4-nitrobenzyl)pyridinium bromide 
• 26199-99-5 4-(4-nitrobenzyl)pyridine N-oxide 
• 108-89-4 picoline 
• 2116-65-6 4-benzyl pyridine 
• 1083-48-3 4-Nitrobenzylpyridin 

Downstream Products

• 178809-75-1 4-(1-hydroxy-1-(4-pyridyl)methyl)-1-nitrobenzene 
• 178809-76-2 (4-Nitro-phenyl)-(1-oxy-pyridin-4-yl)-methanol 
• 16887-79-9 sodium pyridine-4-carboxylate 
• 39066-35-8 4-(3-cyano-4-hydroxybenzoyl)pyridine 
• 170893-64-8 (4-aminophenyl)( pyridin-4-yl)methanone 

Relevant articles and documents

An environmentally benign benzylic oxidation catalyzed by hypervalent iodine intermediate in water

An effective and environmentally benign benzylic oxidation for transition of alkylarenes into the corresponding carbonyl compounds was reported. Alkylarenes were mixed and stirred with potassium bromide, m-chloroperbenzoic acid and a catalytic amount of iodobenzene in water at 60 °C for several hours, a series of the corresponding carbonyl compounds was obtained in moderate to good yields. In the reaction, iodobenzene was first oxidized by m-chloroperbenzoic acid into the hypervalent iodine intermediate which then reacted with potassium bromide to form the key radical initiator for the benzylic oxidation.

Rapid formation of nitrogen-doped carbon foams by self-foaming as metal-free catalysts for selective oxidation of aromatic alkanes

Porous carbon materials have attracted considerable interest as metal-free catalysts. In this study, we report a nitrogen-doped and nanofiber-based porous carbon foam produced via an efficient and facile self-foaming approach and its subsequent pyrolysis; in this approach, carbon dioxide-rich ethanolamine serves as the foaming agent, N source and polymerization catalyst. Meanwhile resorcinol and formaldehyde are used as carbon sources. Carbon dioxide-rich ethanolamine plays a crucial role in the release of gas as well as initiating polymerization on the interfaces of bubbles, which directs the formation of polymer foam. The N-doped carbon foam can be a highly active metal-free heterogeneous catalyst to promote selective oxidation of the benzyl group to the corresponding phenone. In addition, the carbon foams are easily cast with different morphologies. Notably, the prepared carbon foam is fabricated as a monolithic reactor for the oxidation reaction, which also exhibits good catalytic performances in the scale-up experiment.

An efficient approach for enhancing the catalytic activity of Ni-MOF-74: Via a relay catalyst system for the selective oxidation of benzylic C-H bonds under mild conditions

Although nickel-based materials exhibit similar catalytic activity to palladium in organic synthesis, the selective oxidation of inert C-H bonds in the absence of other co-catalysts remains a largely unsolved challenge. This paper introduces a facile and efficient approach for enhancing the catalytic activity of Ni-MOF-74 with [bmim]Br via a relay catalysis strategy, which is excellent for the selective oxidation of benzylic C-H bonds. Notably, the catalyst recycling and scale up experiments demonstrated the practicability of the protocol. This method combines the catalytic advantages of MOFs and ionic liquids (ILs), and provides an insight into oxidation reactions by cheap and efficient Ni-based catalysts.