390824-41-6

Basic information

• Product Name: [C₆F₅Hg(N(CH₂CH₂P(C₆H₅)2)3)]⁽¹⁺⁾*CF₃SO₃^(1-)*CH₂Cl₂=[C₆F₅Hg(N(CH₂CH₂P(C₆H₅)2)3)][CF₃SO₃]*CH₂Cl₂
• CAS NO: 390824-41-6
• Molecular Weight: 1255.37
• Mol File: 390824-41-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [C₆F₅Hg(N(CH₂CH₂P(C₆H₅)2)3)]⁽¹⁺⁾*CF₃SO₃^(1-)*CH₂Cl₂=[C₆F₅Hg(N(CH₂CH₂P(C₆H₅)2)3)][CF₃SO₃]*CH₂Cl₂(CAS DataBase Reference)
• NIST Chemistry Reference: [C₆F₅Hg(N(CH₂CH₂P(C₆H₅)2)3)]⁽¹⁺⁾*CF₃SO₃^(1-)*CH₂Cl₂=[C₆F₅Hg(N(CH₂CH₂P(C₆H₅)2)3)][CF₃SO₃]*CH₂Cl₂(390824-41-6)
• EPA Substance Registry System: [C₆F₅Hg(N(CH₂CH₂P(C₆H₅)2)3)]⁽¹⁺⁾*CF₃SO₃^(1-)*CH₂Cl₂=[C₆F₅Hg(N(CH₂CH₂P(C₆H₅)2)3)][CF₃SO₃]*CH₂Cl₂(390824-41-6)

Safety Data

• Hazardous Substances Data: 390824-41-6(Hazardous Substances Data)

Upstream product

• 75-09-2 dichloromethane 
• 15114-55-3 tris(2-(diphenylphosphino)ethyl)amine 
• 2923-28-6 silver trifluoromethanesulfonate 
• 828-72-8 pentafluorophenylmercury bromide 

Relevant articles and documents

Synthesis, characterization and X-ray structure of the organomercurial complex [Hg(C6F5)(np3)](CF3SO3), np3=N(CH2CH2PPh2)3

The tetrahedral complex [Hg(C6F5)(np3)](CF3SO3), np3=N(CH2CH2PPh2)3 has been prepared and characterized by single-crystal diffraction study and NMR spectroscopy (1H, 31P, 199Hg). The crystal structure consists of [Hg(C6F5)(np3)]+ cations, (CF3SO3)- anions and dichloromethane solvent molecules. In the cation the mercury atom is coordinated to the three phosphorus atoms of the np3 ligand and by a C6F5 molecule with a geometry very close to that of tetrahedral. The NMR measurements, in dichloromethane solution at room temperature, are fully consistent, showing the formation of linkages between the Hg(C6F5) fragment and the three phosphorus atoms of the np3, which are non-labile in the NMR time scale.