39105-81-2Relevant articles and documents
Preparation of alkyltrifluoroborates via Matteson Hydroboration Method
Zillman, David J.,Cole, Thomas E.
, p. 159 - 165 (2018/04/05)
An efficient one-pot method for synthesis of simple alkyltrifluoroborate salts has been developed. Alkyldichloroboranes, prepared by the Matteson Hydroboration Method using in situ generated HBCl2, were esterified with 2-propanol, treated with
Interactions of C?F Bonds with Hydridoboranes: Reduction, Borylation and Friedel–Crafts Alkylation
Bamford, Karlee L.,Chitnis, Saurabh S.,Qu, Zheng-wang,Stephan, Douglas W.
supporting information, p. 16014 - 16018 (2018/10/15)
The stoichiometric reactions of the alkylfluorides 1-fluoroadamantane (Ad-F), fluorocyclohexane (Cy-F), 1-fluoropentane (Pent-F) and benzyl fluorides with secondary boranes pinacolborane (HBpin), catecholborane (HBcat), 9-borabicyclo(3.3.1)nonane (9-BBN)
B,B-dihaloalkylboranes as efficient reagents for the stereoselective synthesis of Syn-aldols
Ramachandran, P. Veeraraghavan,Wei-Chu, Xu,Brown, Herbert C.
, p. 769 - 772 (2007/10/03)
The easily synthesized B,B-dihaloalkylboranes, in the presence of either Et3N or i-Pr2NEt, converts ethyl ketones, RCOEt, to 96-≤ 99% Z-enolates, converted by aldehydes to essentially pure syn-aldols.