39123-62-1

Basic information

• Product Name: 3-(4-METHOXYPHENYL)-2-THIOXOTETRAHYDRO-4H-IMIDAZOL-4-ONE
• Synonyms: 3-(4-METHOXYPHENYL)-2-THIOXOTETRAHYDRO-4H-IMIDAZOL-4-ONE;3-(4-methoxyphenyl)-2-thioxoimidazolidin-4-one
• CAS NO: 39123-62-1
• Molecular Formula: C₁₀H₁₀N₂O₂S
• Molecular Weight: 222.26
• Mol File: 39123-62-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 352.6°C at 760 mmHg
• Flash Point: 167°C
• Appearance: /
• Density: 1.39g/cm³
• Vapor Pressure: 3.8E-05mmHg at 25°C
• Refractive Index: 1.671
• CAS DataBase Reference: 3-(4-METHOXYPHENYL)-2-THIOXOTETRAHYDRO-4H-IMIDAZOL-4-ONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-METHOXYPHENYL)-2-THIOXOTETRAHYDRO-4H-IMIDAZOL-4-ONE(39123-62-1)
• EPA Substance Registry System: 3-(4-METHOXYPHENYL)-2-THIOXOTETRAHYDRO-4H-IMIDAZOL-4-ONE(39123-62-1)

Safety Data

• Hazardous Substances Data: 39123-62-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H10N2O2S/c1-14-8-4-2-7(3-5-8)12-9(13)6-11-10(12)15/h2-5H,6H2,1H3,(H,11,15)

Upstream product

• 75390-41-9 Tetra-p-anisidyl-oxalamidin 
• 99006-59-4 {3-(4-Methoxy-phenyl)-4,5-bis-[(Z)-4-methoxy-phenylimino]-2-thioxo-imidazolidin-1-yl}-acetic acid ethyl ester 
• 5349-28-0 thiocyanato-acetic acid ethyl ester 
• 104-94-9 4-methoxy-aniline 
• 2284-20-0 4-Methoxyphenyl isothiocyanate 
• 56-40-6 glycine 
• 24066-82-8 ethyl 2-isothiocyanatoacetate 
• 459-73-4 GlyOEt*HCl 

Downstream Products

• 110074-57-2 C₅H₅Ti(CH₃OC₆H₄C₃H₂N₂OS)2Cl 
• 110090-68-1 C₅H₅Ti(CH₃OC₆H₄C₃H₂N₂OS)3 
• 110074-56-1 C₅H₅Ti(CH₃OC₆H₄C₃H₂N₂OS)Cl₂ 

Relevant articles and documents

Three types of copper derivatives formed by CuCl2·2H2O interaction with (Z)-3-aryl-2-(methylthio)-5-(pyridine-2-ylmethylene)-3,5-dihydro-4 H -imidazol-4-ones

The reactions of (Z)-3-aryl-2-(methylthio)-5-(pyridine-2-ylmethylene)-3,5-dihydro-4H-imidazol-4-ones (3) with CuCl2·2H2O in the presence of a reducing solvent (alcohol or dimethylformamide (DMF)) produce three types of Cu-containing compounds: two Cu complexes with a composition of CuII(3)Cl2 (4) and CuI(3)Cl (5) as well as a salt (3 + H)+CuICl2- (6) in a 4?:?5?:?6 ratio depending on the substituent at the N(3) nitrogen atom of the ligand moiety. In non-reducing solvents (dimethyl sulfoxide (DMSO) and CHCl3/acetone), only complexes 4 were formed, All three Cu derivatives (4, 5, and 6) were characterized by single-crystal X-ray diffraction, UV/vis spectroscopy, and electrochemistry data. Convenient electrochemical and UV-vis spectral criteria were recorded, which made it possible to distinguish between the different Cu-containing compounds. Based on the electron spectroscopy and electron paramagnetic resonance (EPR) data, a possible scheme for the formation of compounds 4-6 was proposed, including the initial coordination of copper(ii) chloride with an organic ligand, the subsequent reduction of the resulting complex 4 by DMF with the formation of salt 6, and the further transition of salt 6 into the complex 5. This journal is

On the Reaction of Oxalic Amidines with Carbonic Acid Derived Heterocumulenes to Imidazolidine-Derivatives

A useful synthetic route to nonsymmetric derivatives of imidazolidine (derivatives of parabanic acid) is demonstrated by the reaction of tetraarylated oxalic amidines 1 with different alkyl- and aryl substituted isothiocyanates 4, isoselenocyanates 31, and carbodiimides 30.Acylisothiocyanates 9 react differently leading to a mixture of three cycloacylation products 12, 13 and 14.Silylated heterocumulenes such as 25 and 26 react with 1 to give 28 and 29 transsilylation.Based on the 13C-n.m.r. spectroscopic investigation of the reaction between 1a and methyl isothiocyanate and phenyl isothiocyanate respectively a mechanism is proposed.