39193-85-6

Basic information

• Product Name: 3,3'-DIMETHOXYBENZOPHENONE
• Synonyms: 3,3'-DIMETHOXYBENZOPHENONE
• CAS NO: 39193-85-6
• Molecular Formula: C₁₅H₁₄O₃
• Molecular Weight: 242.27
• Mol File: 39193-85-6.mol
• Article Data: 25

Chemical Properties

• Boiling Point: 395.459°C at 760 mmHg
• Flash Point: 184.535°C
• Appearance: /
• Density: 1.124g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.557
• CAS DataBase Reference: 3,3'-DIMETHOXYBENZOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3'-DIMETHOXYBENZOPHENONE(39193-85-6)
• EPA Substance Registry System: 3,3'-DIMETHOXYBENZOPHENONE(39193-85-6)

Safety Data

• Hazardous Substances Data: 39193-85-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H14O3/c1-17-13-7-3-5-11(9-13)15(16)12-6-4-8-14(10-12)18-2/h3-10H,1-2H3

Upstream product

• 108838-47-7 4-Methoxy-2-(3-methoxybenzoyl)benzoic acid 
• 2398-37-0 3-methoxyphenyl bromide 
• 1711-05-3 m-anisoyl chloride 
• 124-38-9 carbon dioxide 
• 766-85-8 3-methoxy-1-iodobenzene 
• 13939-06-5 molybdenum hexacarbonyl 
• 119072-55-8 tert-butylisonitrile 
• 10365-98-7 3-methoxyphenylboronic acid 
• 541-41-3 chloroformic acid ethyl ester 
• 201230-82-2 carbon monoxide 
• 36282-40-3 (3-methoxyphenyl)magnesium bromide 
• 98-86-2 acetophenone 
• 40101-17-5 3,3'-dimethoxybenzil 
• 79-37-8 oxalyl dichloride 

Downstream Products

• 120553-09-5 3,3-bis(3-methoxyphenyl)acrylaldehyde 
• 144617-66-3 3,3-Bis-(3-methoxy-phenyl)-acrylonitrile 
• 574738-14-0 ethyl 3,3-bis-(3-methoxyphenyl)-3-hydroxypropionate 
• 113260-28-9 bis(3-methoxyphenyl)<(trimethylsily)oxy>acetonitrile 

Relevant articles and documents

Mechanochemical Grignard Reactions with Gaseous CO2 and Sodium Methyl Carbonate**

A one-pot, three-step protocol for the preparation of Grignard reagents from organobromides in a ball mill and their subsequent reactions with gaseous carbon dioxide (CO2) or sodium methyl carbonate providing aryl and alkyl carboxylic acids in up to 82 % yield is reported. Noteworthy are the short reaction times and the significantly reduced solvent amounts [2.0 equiv. for liquid assisted grinding (LAG) conditions]. Unexpectedly, aryl bromides with methoxy substituents lead to symmetric ketones as major products.

Photo-induced phosphorus radical involved semipinacol rearrangement reaction: Highly synthesis of γ-oxo-phosphonates

Hydroxyphosphoric acids display the unique biological activities, and they have some attractive prospects as clinical drug moleculars. Herein, a new approach for the synthesis of γ-oxo-phosphonates (the precursor of hydroxyphosphoric acid) has been established through the semipinacol rearrangement tactic involved the photo-induced phosphorus radical process. Most important, this transformation is avoid of the external oxidants, and occurs very well under the sunlight irradiation, meanwhile the γ-oxo-phosphonate was easily derivatized to obtain γ-hydroxyphosphoric acid, thus highlights the synthesis value of this method.

Palladium/Copper-Catalyzed Oxidative Coupling of Arylboronic Acids with Isocyanides: Selective Routes to Amides and Diaryl Ketones

An efficient and alternative oxidative cross-coupling strategy starting from arylboronic acids and isocyanides for the selective synthesis of amides and diaryl ketones with palladium/copper catalysis is developed. Various substituted benzamides and benzop