39213-29-1Relevant articles and documents
Single-Electron Transfer from Dimsyl Anion in the Alkylation of Phenols
Rohe, Samantha,Révol, Guillaume,Marmin, Thomas,Barriault, Daniel,Barriault, Louis
, p. 2806 - 2813 (2020)
While attempting to synthesize biaryl ethers we discovered the inadvertent formation of a methylsulfoxylmethyl ether byproduct. Formation of this unexpected byproduct presented an opportunity to streamline the synthesis of methylsulfoxylmethyl ethers. Mechanistic studies suggest a radical pathway with dimsyl potassium as a reducing agent.