39215-21-9Relevant articles and documents
GENERATION AND TRAPPING OF 2,3-NAPHTHOQUINONE
Horak, V.,Foster, F. V.,Levie, R. de,Jones, J. W.,Svoronos, P.
, p. 3577 - 3578 (1981)
2,3-Naphthoquinone generated from 2,3-dihydroxynaphthalene was trapped with cyclopentadiene and its properties examined by dc polarography and cyclic voltametry.
Oxidative Coupling Reactions of Phenols with FeCl3 in the Solid State
Toda, Fumio,Tanaka, Koichi,Iwata, Shinji
, p. 3007 - 3009 (1989)
Some oxidative coupling reactions of phenols with FeCl3 are faster and more efficient in the solid state than in solution.Some coupling reactions in the solid state are accelerated by irradiation with ultrasound.Some coupling reactions are achieved by using a catalytic amount of FeCl3.
Solvent-controlled selective synthesis of biphenols and quinones: Via oxidative coupling of phenols
More, Nagnath Yadav,Jeganmohan, Masilamani
supporting information, p. 9616 - 9619 (2017/09/01)
A regioselective synthesis of unsymmetrical and symmetrical biphenols and binaphthols via oxidative coupling of phenols or naphthols in the presence of K2S2O8 in CF3COOH under ambient conditions is described. Interestingly, the 1:1 ratio of H2O and CH3CN solvent mixtures at 80 °C instead of CF3COOH provided substituted unsymmetrical quinones. A gram-scale synthesis of biphenols and binaphthols was demonstrated.
Polymers of intrinsic microporosity with dinaphthyl and thianthrene segments
Du, Naiying,Robertson, Gilles P.,Pinnau, Ingo,Guiver, Michael D.
experimental part, p. 8580 - 8587 (2011/11/12)
Novel intrinsically microporous homopolymers and copolymers derived from PIM-1 monomers (5,5,6,6-tetrahydroxy-3,3,3,3-tetramethylspirobisindane and 2,3,5,6-tetrafluoroterephthalonitrile) with two additional monomers- tetrahydroxydinaphthyl and tetrafluorotetraoxide thianthrene-are reported as potential materials for membrane-based gas separations. The resulting copolymers prevent efficient space packing of the stiff polymer chains and consequently exhibit analogous behavior to that of PIM-1, the most widely reported polymer in this class of materials. In addition, the copolymerization provides high molecular weight copolymers and low polydispersity if the polymerization reactions were conducted at elevated temperature for an extended period of time. Detailed structural characterization of the new monomers and polymers was determined by 1H and 19F nuclear magnetic resonance spectroscopy (NMR). The thermal properties were detected by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Polymer free volume was calculated from the polymer density and specific van der Waals volume. Under the same testing conditions, the homopolymer containing thianthrene units and most of the analogous copolymers have an excellent combination of properties with good film-forming characteristics. The gas transport properties show higher selectivity for gas pairs such as O 2/N2, CO2/N2, and H 2/N2 with a corresponding decrease in permeability compared to PIM-1. This work also demonstrates that significant improvements in properties may be obtained through copolymers of intrinsic microporosity (CoPIM)s. Furthermore, this work extends the spectrum of high molecular weight soluble PIMs beyond those reported previously.