3944-16-9

Basic information

• Product Name: Silacyclopentane, 1,1-diphenyl-
• CAS NO: 3944-16-9
• Molecular Formula: C16H18Si
• Molecular Weight: 238.404
• Mol File: 3944-16-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silacyclopentane, 1,1-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silacyclopentane, 1,1-diphenyl-(3944-16-9)
• EPA Substance Registry System: Silacyclopentane, 1,1-diphenyl-(3944-16-9)

Safety Data

• Hazardous Substances Data: 3944-16-9(Hazardous Substances Data)

Upstream product

• 2123-72-0 1,4-dilithiobutane 
• 80-10-4 diphenylsilyl dichloride 
• 2406-33-9 1,1-dichlorosilacyclopentane 
• 2736-09-6 1,1-diphenyl-1-silacyclohexanone-2 
• 1072-54-4 1,1-dimethyl-1-silacyclopentane 
• 75-77-4 chloro-trimethyl-silane 
• 591-51-5 phenyllithium 
• 110-52-1 1,4-dibromo-butane 
• 110-56-5 1,4-dichlorobutane 

Relevant articles and documents

?-Silicon-effect-promoted intermolecular site-selective C(sp3)-H amination with dirhodium nitrenes

A dirhodium-catalyzed, ?-selective C-H amination of organosilicon compounds has been developed. Primary C(sp3)-H bonds of silylethyl groups and secondary C(sp3)-H bonds of silacycloalkanes can be selectively converted to C-N bonds at the ?-position of the silicon atoms. The experimental data and theoretical calculations indicate that the strong s-donor ability of the carbon-silicon bonds is responsible for the ?-selectivity. Kinetic isotope effects clearly demonstrate that the C-H bond cleavage step is not turnover-limiting, but selectivity-determining.

UEBER DIE AUSTAUSCHBARKEIT VON METHYL- UND PHENYLGRUPPEN AM SILICIUM VON SILACYCLOPENTAN BEI DER EINWIRKUNG VON ALKYL- UND ARYLLITHIUMVERBINDUNGEN IN DIETHYLETHER ODER TETRAHYDROFURAN

A degenerate ligand exchange, presumably via an ate-complex intermediate, takes place upon treatment of 1,1-dimethyl- (3) and 1,1-diphenyl-silacyclopentane (17) in THF-d8 with perdeuteriomethyllithium (4-d3) or perdeuteriophenyllithium (15-d5), respective