39491-73-1Relevant articles and documents
Unprecedented elimination of conjugated phenylthioether groups by low-valent titanocene
Ribeiro, Nigel,Fetzer, Ludivine,Streiff, Stéphane,Désaubry, Laurent
, p. 2928 - 2930 (2010)
The first thioether elimination reaction utilizing a low-valent titanocene has been discovered. This reaction occurs under mild conditions and affords stereospecifically a variety of dienes and styrenes. Our data suggest that this new reaction involves an
Divergent Reactivity of α,α-Disubstituted Alkenyl Hydrazones: Bench Stable Cyclopropylcarbinyl Equivalents
Ritchie, Nina F. C.,Zahara, Adam J.,Wilkerson-Hill, Sidney M.
supporting information, p. 2101 - 2106 (2022/02/14)
Herein we report the divergent reactivity of 2,2-dialkyl-3-(E)-alkenyl N-tosylhydrazones using Pd-catalyzed cross-coupling conditions, which enable the Z-selective synthesis of 3-aryl-1,4-dienes and gem-dialkyl vinylcyclopropanes. We found that the dialky
Transition-metal-free synthesis of vicinal triborated compounds and selective functionalisation of the internal C-B bond
Davenport, Elliot,Fernandez, Elena
supporting information, p. 10104 - 10107 (2018/09/18)
1,2,3-Triborated compounds can be prepared by simple nucleophilic borylation of 1,3-dienes, without the assistance of metal catalysts. Selective functionalisation of the internal C-B bond of the 1,2,3-triborated compounds, through cross-coupling with aryl