39566-17-1Relevant articles and documents
Synthesis of Trifluoromethylthiolated Alkenes and Ketones by Decarboxylative Functionalization of Cinnamic Acids
Pan, Shen,Huang, Yangen,Qing, Feng-Ling
, p. 2854 - 2858 (2016)
A tunable decarboxylative trifluoromethylthiolation of cinnamic acids with AgSCF3 was developed to afford trifluoromethylthiolated alkenes or ketones by using transition metal-mediated conditions.
Ag(I)-Mediated Oxidative Radical Tri?fluoromethylthiolation of Alkenes
Fang, Ge,Hong, Jianquan,Huang, Shuai,Liu, Yang,Yang, Yupeng,Zhang, Wei,Zheng, Changge
supporting information, p. 1324 - 1328 (2019/06/19)
A simple, mild, and efficient method for an oxidative radical tri?fluoromethylthiolation of alkenes through AgSCF 3 /K 2 S 2 O 8 system has been developed. This reaction provides a straightforward way to synthesize a variety of useful α-SCF 3 -substituted ketone compounds from a wide range of alkenes in moderate to good yields.
Cu(II)-Mediated Decarboxylative Trifluoromethylthiolation of α,β-Unsaturated Carboxylic Acids
Cheng, Zhi-Fei,Tao, Ting-Ting,Feng, Yi-Si,Tang, Wei-Ke,Xu, Jun,Dai, Jian-Jun,Xu, Hua-Jian
, p. 499 - 504 (2018/02/19)
A tunable method for the direct trifluoromethylthiolation of α,β-unsaturated carboxylic acids was developed to afford trifluoromethylthiolated ketones or alkenes. The reaction proceeds smoothly under mild conditions and shows an excellent functional group tolerance.
