39728-19-3

Basic information

• Product Name: 3-Undecanone, 1-phenyl-
• CAS NO: 39728-19-3
• Molecular Formula: C17H26O
• Molecular Weight: 246.393
• Mol File: 39728-19-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3-Undecanone, 1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Undecanone, 1-phenyl-(39728-19-3)
• EPA Substance Registry System: 3-Undecanone, 1-phenyl-(39728-19-3)

Safety Data

• Hazardous Substances Data: 39728-19-3(Hazardous Substances Data)

Upstream product

• 39728-27-3 (±)-1-phenylundecan-3-ol 
• 103-83-3 N,N'-dimethylbenzylamine 
• 645-45-4 hydrocinnamic acid chloride 
• 39727-94-1 Benzyl-dimethyl-(2-oxo-decyl)-ammonium; bromide 
• 39727-88-3 1-bromo-2-decanone 
• 111-66-0 oct-1-ene 
• 256379-28-9 N-(3-methyl-2-pyridyl)-N-[(E)-3-phenyl-2-propenyl]amine 
• 108-86-1 bromobenzene 
• 2038-57-5 3-Phenylpropan-1-amine 
• 39728-03-5 (1-Benzyl-2-oxo-decyl)-trimethyl-ammonium; iodide 

Downstream Products

• 6742-54-7 undecylbenzene 
• 39728-27-3 (±)-1-phenylundecan-3-ol 

Relevant articles and documents

Stereodivergent synthesis of alkenes by controllable syn-/anti-fragmentation of β-hydroxysulfonyl intermediates

The reduction of the carbonyl group in acylated trifluoroethyl alkanesulfonates follows the Felkin-Ahn selectivity, and the so-formed diastereomeric β-hydroxysulfonyl intermediates undergo syn- and anti-fragmentation, depending on the reaction conditions. In effect, isomeric E- and Z-alkenes are formed in a stereodivergent manner, which mimics the mechanistic manifold of the Peterson olefination.

C-H and C-C bond activation of primary amines through dehydrogenation and transimination

Matrix presented Dehydrogenation and subsequent transimination of primary amines offer a new pathway for C-H bond activation, ortho-alkylation, and C-C bond activation to afford a variety of ketones in the reaction of 1-alkene by a cocatalyt system of Rh(I) and 2-amino-3-picoline.

Oxidation of sec-Alcohols to the Corresponding Ketones by Corynebacterium equi

Corinebacterium equi IFO 3730 was found to oxidize a wide variety of sec-alcohols, including alkanols, substituted alkanols, alkenols and cyclic alcohols, in moderate to high yields.Among them, the sec-alcohols which have longer carbon chains were oxidized more smoothly than those with smaller numbers of carbon.Although both enantiomers of unsymmetrically disubstituted carbinols were oxidized, the S form of 2-dodecanol was converted to the corresponding ketone a little faster than the other enantiomer.