39847-39-7

Basic information

• Product Name: BIS(1,1,2,2,3,3,4,4,4-NONAFLUORO-1-BUTANESULFONYL)IMIDE
• Synonyms: 1,1,2,2,3,3,4,4,4-nonafluoro-N-[(nonafluorobutyl)sulfonyl]-1-Butanesulfonamide;BIS(1,1,2,2,3,3,4,4,4-NONAFLUORO-1-BUTANESULFONYL)IMIDE;Bis(1,1,2,2,3,3,4,4,4-nonafluoro-1-butaneulfonyl)imide
• CAS NO: 39847-39-7
• Molecular Formula: C₈HF₁₈NO₄S₂
• Molecular Weight: 581.2
• Mol File: 39847-39-7.mol
• Article Data: 6

Chemical Properties

• Melting Point: 120.7 °C
• Boiling Point: 274.061°C at 760 mmHg
• Flash Point: 119.548°C
• Appearance: /
• Density: 1.875g/cm³
• Vapor Pressure: 0.006mmHg at 25°C
• Refractive Index: 1.326
• PKA: -8.68±0.40(Predicted)
• CAS DataBase Reference: BIS(1,1,2,2,3,3,4,4,4-NONAFLUORO-1-BUTANESULFONYL)IMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: BIS(1,1,2,2,3,3,4,4,4-NONAFLUORO-1-BUTANESULFONYL)IMIDE(39847-39-7)
• EPA Substance Registry System: BIS(1,1,2,2,3,3,4,4,4-NONAFLUORO-1-BUTANESULFONYL)IMIDE(39847-39-7)

Safety Data

• Hazardous Substances Data: 39847-39-7(Hazardous Substances Data)

Usage

Description

BIS(1,1,2,2,3,3,4,4,4-NONAFLUORO-1-BUTANESULFONYL)IMIDE, also known as F7SIA, is a fluorinated compound with a unique chemical structure that provides it with exceptional properties. It is nonflammable, highly stable, and possesses strong chemical resistance and thermal stability. These characteristics make F7SIA a versatile compound suitable for a wide range of applications in energy storage, thermal management, and organic synthesis.

Uses

Used in Energy Storage Industry:
F7SIA is used as an electrolyte in lithium-ion batteries for its nonflammable and highly stable nature. It enhances the safety and performance of energy storage devices by providing a stable medium for ion conduction, leading to improved battery life and reliability.
Used in Organic Synthesis:
F7SIA is used as a solvent in organic synthesis due to its strong chemical resistance and ability to dissolve a wide range of compounds. This makes it an ideal choice for various chemical reactions, facilitating the synthesis of complex organic molecules and improving reaction yields.
Used in Thermal Management Industry:
F7SIA is used as a heat transfer medium in thermal management applications, such as cooling systems for electronic devices and industrial processes. Its high thermal stability and nonflammable properties make it a safe and efficient choice for managing heat dissipation and maintaining optimal operating temperatures.

InChI:InChI=1/C8HF18NO4S2/c9-1(10,5(17,18)19)3(13,14)7(23,24)32(28,29)27-33(30,31)8(25,26)4(15,16)2(11,12)6(20,21)22/h27H

Upstream product

• 375-72-4 Nonafluorobutanesulfonyl fluoride 

Downstream Products

• 39847-43-3 N-methyl bis[(1,1,2,2,3,3,4,4,4-nonafluorobutane)sulfonyl]imide 
• 636597-07-4 4-hydroxy-3,5-dimethyl phenyl dimethyl sulphonium bis-perfluorobutane sulphonimide 

Relevant articles and documents

Multi-functional fluorinated ionic liquid infused slippery surfaces with dual-responsive wettability switching and self-repairing

Stimuli responsive slippery surfaces with controllable wettability have attracted much attention due to their potential application in many fields. However, most of these surfaces only adopted paraffin as the lubricant oil and achieved wettability transformation just by heating. In addition, the self-repairing properties of smart slippery surfaces have rarely been reported. Hence, challenges still remain in fabricating multiple responsive slippery surfaces based on other lubricants possessing self-repairing properties. Here, a smart slippery surface with controllable wettability was fabricated by using solid/liquid fluorinated ionic liquids (FILs) as lubricants and fluoropolymer films as the underlying substrates. The FIL, a thermo-responsive phase-transition material, was synthesized by ionic exchange and the substrate exhibited good self-repairing properties and magnetic-thermal and photo-thermal responses. By tuning the substrate temperature under light irradiation or magnetic field to change the phase state of the FIL, the surface could realize wettability conversion. Besides, the responsive temperature can be adjusted by tuning the melting temperature (Tm) of the FIL. The FIL was first synthesized and there was no report employing FILs as the lubricants to realize the wettability change of slippery surfaces. This work provided a new type of lubricant to prepare intelligent slippery surfaces, thus advancing the application of slippery surfaces in liquid transport devices.

New and easily accessible nitrogen acyclic gold(I) carbenes: Structure and application in the gold-catalyzed phenol synthesis as well as the hydration of alkynes

A series of gold(I) isonitrile complexes were prepared and converted to the corresponding diaminocarbene gold(I) complexes by reactions with primary and symmetrical secondary amines. Twelve crystal structure analyses of the gold(I) complexes could be obtained, in addition NMR studies allowed an analysis of the different diastereomers present in solution. In the gold-catalyzed phenol synthesis these complexes were very successful as pre-catalysts, reaching an unprecedented 3050 turnovers with a problematic substrate. Good conversions in the hydration of phenylacetylene could also be achieved.

Synthesis of symmetric and dissymetric bisperfluoroalkanesulfonylimides and evaluation of their inhibition on bovine carbonic anhydrase

This study describes a synthesis of symmetric and dissymmetric bis[(perfluoroalkane)-sulfonyl]imides by the reaction of the sodium salt of perfluoroalkanesulfonamide RFSO2NH-Na + (RF = C4F9, C6F 13, C8F17) with hexamethyldisilazane and perfluoroalkanesulfonylfluoride RFSO2F (RF - C4F9, C6F13, C8F 17). They are obtained, in two steps, in moderate overall yield. Moreover, this paper provides a study of their inhibition on bovine carbonic anhydrase.