39869-70-0

Basic information

• Product Name: 7,7-dimethoxybicyclo[2.2.1]heptane
• Synonyms: 7,7-Dimethoxybicyclo[2.2.1]heptane; bicyclo[2.2.1]heptane, 7,7-dimethoxy-
• CAS NO: 39869-70-0
• Molecular Formula: C₉H₁₆O₂
• Molecular Weight: 156.2221
• Mol File: 39869-70-0.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 181.758°C at 760 mmHg
• Flash Point: 53.124°C
• Density: 1.013g/cm³
• Vapor Pressure: 1.141mmHg at 25°C
• Refractive Index: 1.471
• CAS DataBase Reference: 7,7-dimethoxybicyclo[2.2.1]heptane(CAS DataBase Reference)
• NIST Chemistry Reference: 7,7-dimethoxybicyclo[2.2.1]heptane(39869-70-0)
• EPA Substance Registry System: 7,7-dimethoxybicyclo[2.2.1]heptane(39869-70-0)

Safety Data

• Hazardous Substances Data: 39869-70-0(Hazardous Substances Data)

Upstream product

• 10218-02-7 7-norbornanone 
• 10265-39-1 (1R,4S)-7,7-Dimethoxy-bicyclo[2.2.1]heptan-2-one 
• 10265-41-5 7,7-dimethoxybicyclo<2.2.1>heptan-exo-2-ol 
• 73997-59-8 7,7-dimethoxybicyclo<2.2.1>heptan-exo-2-yl half-acid phthalate 
• 19448-78-3 1,2,3,4-tetrachloro-7,7-dimethoxybicyclo<2.2.1>hept-2-ene 
• 67-56-1 methanol 
• 71442-88-1 7,7-bis(trifluoromethylsulfonyloxy)norbornane 
• 875-04-7 7,7-dimethoxybicyclo<2.2.1>heptene 
• 53329-08-1 C₁₆H₂₂N₂O₄S 

Downstream Products

• 7076-83-7 exo-Tricyclo<3.2.1.0^2.4>octanon-(8) 
• 67-56-1 methanol 
• 108-94-1 cyclohexanone 

Relevant articles and documents

The Octant Rule. 7. Deuterium as an Octant Pertuber

(1S)-exo-2-Deuteriobicycloheptan-7-one (1) and (1S)-endo-2-deuteriobicycloheptan-7-one (2) were synthesized, and their circular dichroism spectra were measured and analyzed.Both ketones show dissignate Cotton effects near 295 nm corresponding to their n-?* electronic transitions: 1 (Δε296 = +0.033) and 2 (Δε292 = +0.132).The nature of the isotopic perturbation on the n-?* transitions of 1 and 2, related β-deuterioadamantanones and cyclohexanones, and α-deuteriocyclohexanones is treated theoretically.The net contribution to the sign of the rotatory strength is determined by the relatively more consignate contribution on the C-H bond that is located in an oppositely signed octant relative to the C-D bond.