39992-52-4Relevant articles and documents
On the oxidation of 3-ethylpentane under GifIV and Gif-orsay conditions
Barton, Derek H. R.,Doller, Dario,Ozbalik, Nubar,Balavoine, Gilbert,Gref, Aurore,Boivin, Jean
, p. 353 - 356 (1990)
The oxidation of 3-ethylpentane under GifIV (and GoAggII) conditions affords, as major product, 3-acetylpentane and not diethylketone as previously reported. The discrepancy is explained by radical chain autoxidation in presence of a weak tertiary C - H bond.
Stereochemistry of the Platinum Catalyzed Hydroformylation of Olefins
Haelg, Paul,Consiglio, Giambattista,Pino, Piero
, p. 1865 - 1869 (2007/10/02)
The deuterioformylation of (Z)- or (E)-2-butene catalyzed by Pt(SnCl3)Cl gives predominantly erythro- or threo-1,3-2-2-methylbutanal respectively.Hence, hydroformylation by this catalytic system must take place with cis-stereochemistry.