4009-22-7

Basic information

• Product Name: Benzene, 1,3-pentadiynyl- (9CI)
• Synonyms: Benzene, 1,3-pentadiynyl- (9CI)
• CAS NO: 4009-22-7
• Molecular Formula: C₁₁H₈
• Molecular Weight: 140.18122
• Mol File: 4009-22-7.mol
• Article Data: 10

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzene, 1,3-pentadiynyl- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,3-pentadiynyl- (9CI)(4009-22-7)
• EPA Substance Registry System: Benzene, 1,3-pentadiynyl- (9CI)(4009-22-7)

Safety Data

• Hazardous Substances Data: 4009-22-7(Hazardous Substances Data)

Upstream product

• 2003-82-9 3-bromo-2-propyne 
• 536-74-3 phenylacetylene 
• 101160-52-5 Trifluoro-methanesulfonic acid (Z)-1-phenylethynyl-propenyl ester 
• 90320-91-5 4-Phenyl-butadiin-(1,3)-natrium 
• 74-88-4 methyl iodide 
• 879560-02-8 (1,1-dibromobut-1-en-3-yn-2-yl)benzene 
• 1303963-75-8 (Z)-1-[(1-chloro-2-methyl-4-phenylbut-1-en-3-yn-1-yl)sulfinyl]-4-methylbenzene 
• 1303963-73-6 (E)-1-[(1-chloro-2-methyl-4-phenylbut-1-en-3-yn-1-yl)sulfinyl]-4-methylbenzene 
• 16466-97-0 1-propynylmagnesium bromide 
• 28995-88-2 1-methyl-4-((phenylethynyl)sulfonyl)benzene 
• 6738-06-3 phenylethynylmagnesium bromide 
• 18685-03-5 (E)-1-(4-chlorobut-3-en-1-ynyl)benzene 
• 36038-37-6 3,4,4,4-Tetrachlor-1-phenyl-1-butin 
• 6181-26-6 1-trichloromethyl-3-phenyl-2-propyn-1-ol 

Downstream Products

• 27959-72-4 1-isopropyl-2-methyl-5-phenyl-1H-phosphole 
• 34868-04-7 1-isopropyl-2-methyl-5-phenyl-1H-phosphole 1-sulfide 
• 34862-56-1 2-methyl-1,5-diphenyl-1H-phosphole 1-sulfide 
• 886-66-8 1,4-diphenyl-1,3-butadiyne 
• 2809-69-0 2,4-hexadiyne 

Relevant articles and documents

The Preparation of Unsymmetrical Diacetylenes from Alkenynyl Triflates

Alkenynyl triflates 5 (alkynylvinyl trifluoromethanesulfonates) are readily converted into unsymmetrical diacetylenes 6 in good yields by the base-initiated elimination of trifluoromethanesulfonic acid.

"Anti-Michael addition" of Grignard reagents to sulfonylacetylenes: Synthesis of alkynes

In this work, the addition of Grignard reagents to arylsulfonylacetylenes, which undergoes an "anti-Michael addition", resulting in their alkynylation under very mild conditions is described. The simplicity of the experimental procedure and the functional

One-pot synthesis and functionalization of polyynes via alkylidene carbenoids

A one-pot, two-step method for the synthesis of diynes and triynes is reported. The reaction of a dibromoolefinic precursor with BuLi effects a Fritsch-Buttenberg-Wiechell rearrangement and generates a lithium acetylide intermediate, which is then trapped