40244-26-6

Basic information

• Product Name: Cyclohexene, 1-(1-butenyl)-2,6,6-trimethyl-, (E)-
• CAS NO: 40244-26-6
• Molecular Formula: C13H22
• Molecular Weight: 178.318
• Mol File: 40244-26-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 1-(1-butenyl)-2,6,6-trimethyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 1-(1-butenyl)-2,6,6-trimethyl-, (E)-(40244-26-6)
• EPA Substance Registry System: Cyclohexene, 1-(1-butenyl)-2,6,6-trimethyl-, (E)-(40244-26-6)

Safety Data

• Hazardous Substances Data: 40244-26-6(Hazardous Substances Data)

Upstream product

• 79-77-6 (E)-β-ionone 
• 35156-37-7 Trimethyl-[(E)-1-methyl-3-(2,6,6-trimethyl-cyclohex-1-enyl)-allyloxy]-silane 
• 53319-91-8 (E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-yl acetate 

Relevant articles and documents

A novel reduction reaction for the conversion of aldehydes, ketones and primary, secondary and tertiary alcohols into their corresponding alkanes

A novel one-pot reaction has been developed for the reduction of aldehydes, ketones and primary, secondary and tertiary alcohols into their corresponding alkyl function. This is also the first reported method which can efficiently reduce primary, secondary, or tertiary alcohols, without affecting carbon-carbon double bonds, into their corresponding alkyl function in high yields. The reduction utilises either diethylsilane or n-butylsilane as the reducing agent in the presence of the Lewis acid catalyst tris(pentafluorophenyl)borane.

Pd(0)-Catalyzed Electroreductive Cleavage of Allylic Acetates1

Pd(0)-catalyzed electroreductive cleavage of allylic acetates yielding alkenes and/or allyltrimethylsilanes is described.Deprotection of allyl esters can be performed in the same electrolysis system.