40309-57-7Relevant articles and documents
Silica Metal Oxide Vesicles Catalyze Comprehensive Prebiotic Chemistry
Mattia Bizzarri, Bruno,Botta, Lorenzo,Pérez-Valverde, Maritza Iveth,Saladino, Raffaele,Di Mauro, Ernesto,García-Ruiz, Juan Manuel
, p. 8126 - 8132 (2018/05/29)
It has recently been demonstrated that mineral self-assembled structures catalyzing prebiotic chemical reactions may form in natural waters derived from serpentinization, a geological process widespread in the early stages of Earth-like planets. We have s
AUTOXIDATIVE RINGVERENGUNG VON 1,2-BIS(TRIMETHYLSILOXY)-CYCLOBUTENEN
Heine, Hans-Georg,Hartmann, Willy,Knops, Hans-Joachim,Priesnitz, Uwe
, p. 2635 - 2638 (2007/10/02)
1,2-Bis(trimethylsiloxy)cyclobutenes undergo facile autoxidative ring contraction yielding 1-trimethylsiloxycyclopropane carboxylic acid trimethylsilyl esters as major products.The results are discussed in terms of a mechanism involving electron transfer and intermediate formation of dioxiranes.