40366-99-2

Basic information

• Product Name: N-allyl-N-phenyl-phenylamidine
• Synonyms: N-allyl-N-phenyl-phenylamidine
• CAS NO: 40366-99-2
• Molecular Weight: 236.316
• Mol File: 40366-99-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-allyl-N-phenyl-phenylamidine(CAS DataBase Reference)
• NIST Chemistry Reference: N-allyl-N-phenyl-phenylamidine(40366-99-2)
• EPA Substance Registry System: N-allyl-N-phenyl-phenylamidine(40366-99-2)

Safety Data

• Hazardous Substances Data: 40366-99-2(Hazardous Substances Data)

Upstream product

• 589-09-3 N-allyl-N-phenylamine 
• 100-47-0 benzonitrile 

Downstream Products

• 1527-91-9 N-phenylbenzamidine 
• 1427476-06-9 (+/-)-4-methyl-1,2-diphenyl-4,5-dihydro-1H-imidazole 
• 100-47-0 benzonitrile 
• 589-09-3 N-allyl-N-phenylamine 
• 1397868-47-1 (1,2-diphenyl-1H-imidazol-4-yl)methyl acetate 
• 82672-31-9 4-methyl-1,2-diphenyl-1H-imidazole 
• 1397868-27-7 1-((1,2-diphenyl-4,5-dihydro-1H-imidazol-4-yl)methoxy)-2,2,6,6-tetramethylpiperidine 
• 75378-61-9 1,2-diphenyl-1H-imidazole-4-carbaldehyde 
• 1402238-53-2 (1,2-diphenyl-4,5-dihydro-1H-imidazol-4-yl)methyl acetate 

Relevant articles and documents

Copper-catalyzed intramolecular dehydrogenative aminooxygenation: Direct access to formyl-substituted aromatic N-heterocycles

A direct synthesis of carbaldehydes through intramolecular dehydrogenative aminooxygenation has been developed. The process uses a catalytic amount of copper(II) in DMF or DMA under oxygen and does not require additional oxidants (see scheme). Mechanistic studies suggest that the carbonyl oxygen atom of the aldehyde is derived from oxygen through a copper-mediated oxygen activation process via a peroxy-copper(III) intermediate. Copyright

Cu(II)-mediated aminooxygenation of alkenylimines and alkenylamidines with TEMPO

A method for the synthesis of oxymethyl dihydropyrroles (pyrrolines) and dihydroimidazoles has been developed via Cu(II)-mediated intramolecular aminooxygenation of alkenylimines and alkenylamidines, respectively, with 2,2,6,6-tetramethyl-1-piperidinyloxy radical (TEMPO). Georg Thieme Verlag Stuttgart · New York.