40426-44-6

Basic information

• Product Name: Methyl(2-methyl-3-butene-2-yl) ether
• Synonyms: 3-Methoxy-3-methyl-1-butene;Methyl(2-methyl-3-butene-2-yl) ether
• CAS NO: 40426-44-6
• Molecular Formula: C₆H₁₂O
• Molecular Weight: 0
• Mol File: 40426-44-6.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Methyl(2-methyl-3-butene-2-yl) ether(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl(2-methyl-3-butene-2-yl) ether(40426-44-6)
• EPA Substance Registry System: Methyl(2-methyl-3-butene-2-yl) ether(40426-44-6)

Safety Data

• Hazardous Substances Data: 40426-44-6(Hazardous Substances Data)

Upstream product

• 78-79-5 isoprene 
• 67-56-1 methanol 
• 870-63-3 prenyl bromide 
• 124-41-4 sodium methylate 
• 186581-53-3 diazomethane 
• 115-18-4 2-methyl-3-buten-2-ol 
• 2190-48-9 3-chloro-3-methyl-1-butene 
• 2154-65-6 1,3,5-triphenylverdazyl 
• 19757-86-9 methyl 2,2-dimethyl-3-pentenoate 
• 7664-93-9 sulfuric acid 

Downstream Products

• 16736-42-8 2,7-dimethyl-octa-2,6-diene 
• 35387-63-4 3,3,6-trimethylhepta-1,5-diene 
• 18293-99-7 Prenyltrimethylsilane 
• 22539-80-6 diethyl (3-methylbut-2-enyl)malonate 
• 759-30-8 (dimethyl-1,2 propene-2 yl) propane dioate d'ethyle 
• 57813-20-4 (E)-(methyl-2 butene-2 yl) propane dioate d'ethyle 
• 758-66-7 diethyl 2-(2-methylbut-3-en-2-yl)malonate 

Relevant articles and documents

Intramolecular trapping of an ylide intermediate in the reaction of1:CH2 with an allylic alcohol

The reaction of 1:CH2, generated by the photolysis of CH2N2, with 2-methyl-3-buten-2-ol leads to the formation of several products including 4-methyl-3-penten-1-ol. This product is best explained as the result of rearrangement of an ylide intermediate.

Kinetics and mechanism of monomolecular heterolysis of commercial organohalogen compounds: XLI. Solvent effect on the rate of 3-methyl-3-chloro-1- butene solvolysis. Correlation analysis of solvation effects and role of solvent nucleophilicity

The kinetics of 3-methyl-3-chloro-1-butene solvolysis at 25°C in MeOH, EtOH, BuOH, i-BuOH, PentOH, 2-PrOH, 2-BuOH, HexOH, OctOH, t-BuOH, t-PentOH, cyclohexanol, and allyl alcohol was studied by the verdazyl method; v = k[C 5H9Cl], SN1 + E1 mechanism. The reaction rate shows a satisfactory correlation with the parameter of the solvent ionizing power E T and is independent of the solvent nucleophilicity. 2005 Pleiades Publishing, Inc.

Cycloaddition of Dichloroketene to Allyl Ethers and Thioethers

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