4044-56-8Relevant articles and documents
-
Brown,Hammick
, p. 1395,1397 (1948)
-
Rhodium-catalyzed coupling reaction of aroyl chlorides with alkenes
Sugihara, Toru,Satoh, Tetsuya,Miura, Masahiro,Nomura, Masakatsu
, p. 1765 - 1772 (2007/10/03)
Aroyl chlorides react with acyclic and cyclic alkenes in the presence of a rhodium catalyst to give Mizoroki-Heck type and cyclization products, respectively. A rhodium-ethylene complex, [{RhCl(C2H 4)2}2], showed excellent performance for these reactions. Notably, the reactions can be conducted effectively under base- and phosphane-free conditions.