405215-55-6

Basic information

• Product Name: 1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose
• Synonyms: 1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose
• CAS NO: 405215-55-6
• Molecular Weight: 433.458
• Mol File: 405215-55-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose(405215-55-6)
• EPA Substance Registry System: 1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose(405215-55-6)

Safety Data

• Hazardous Substances Data: 405215-55-6(Hazardous Substances Data)

Upstream product

• 405283-43-4 N-benzyloxycarbonyl-1,4-dideoxy-1,4-imino-2,3-O-isopropylidene-D-allitol 
• 405283-44-5 N-(benzyloxycarbonyl)-1,4-dideoxy-1,4-imino-2,3:5,6-di-O-isopropylidene-D-allitol 
• 405215-53-4 N-benzyloxycarbonyl-2,5-dideoxy-2,5-imino-3,4-O-isopropylidene-L-ribose 
• 501-53-1 benzyl chloroformate 
• 117859-46-8 1,4-Dideoxy-2,3:5,6-di-O-isopropylidene-1,4-imino-D-allitol 
• 37112-31-5 levoglucosenone 
• 405215-54-5 (3aR,4R,6aS)-4-[(S)-Hydroxy-((1S,5R)-4-oxo-6,8-dioxa-bicyclo[3.2.1]oct-2-en-3-yl)-methyl]-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyrrole-5-carboxylic acid benzyl ester 

Downstream Products

• 405215-57-8 (3aR,4S,6aS)-4-{(S)-(tert-Butyl-dimethyl-silanyloxy)-[(1S,4S,5R)-4-(tert-butyl-dimethyl-silanyloxy)-6,8-dioxa-bicyclo[3.2.1]oct-2-en-3-yl]-methyl}-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyrrole-5-carboxylic acid benzyl ester 

Relevant articles and documents

Synthesis of (1→3)-C and homo(1→3)-C-linked imino-disaccharides starting from levoglucosenone and isolevoglucosenone

The reaction of 2,5-(benzyloxycarbonyl)imino-2,5-dideoxy-3,4-O-isopropylidene-L-ribose ((-)-15) with levoglucosenone (5) in the presence of Et2A1I gave a 3,4-dideoxy-D-glycero-hex-3-enopyranos-2-ulose derivative ((-)-16) that was converted into the (1→3)-C-linked imino-disaccharide: methyl 3,4-dideoxy-3-[(1′S)-2′,5′-dideoxy-2′,5′- imino-D-ribitol-1′-C-yl)-α-D-lyxo-hexo-pyranoside ((+)-22). The addition of benzyl alcohol to isolevoglucosenone (3), followed by cross-aldol condensation with 3,6-[tert-butoxycarbonyl]imino-2,3,6trideoxy-4,5-O-isopropylidene-L-arabino- hexose ((+)-30) generated, after water elimination, a single enone ((+)-31) that was converted into a homo-(1→3)-C-linked imino-disaccharide: 3-deoxy-3-(1′,2′,3′,6′-tetradeoxy-3′,6′- imino-L-arabino-hexitol-1′-C-yl)-β-D-galactofuranose (44).