40529-13-3Relevant articles and documents
On the Pyrolysis of Pent-1-ene-4,4,5,5,5-d5
Kopinke, F.-D.,Bach, G.,Ondruschka, B.,Zimmermann, G.
, p. 699 - 707 (2007/10/02)
The distribution of deuterium in the main products of thermal decomposition of pent-1-ene-4,4,5,5,5-d5 at 550 to 650 deg C was studied and interpreted.The results include conclusions on kinetic isotope effects, on relative reactivities of different C-H-bonds, on the proportion of terminal and nonterminal addition of methyl radicals, and on the importance of a radical isomerisation reaction.It was shown that the molecular decomposition (Retro-En-Reaction) cannot successfully compete with the radical way in the temperature range above 600 deg C.
