405919-41-7Relevant articles and documents
A highly active Suzuki catalyst for the synthesis of sterically hindered biaryls: Novel ligand coordination
Yin, Jingjun,Rainka, Matthew P.,Zhang, Xiao-Xiang,Buchwald, Stephen L.
, p. 1162 - 1163 (2002)
A catalyst system for the preparation of biaryls containing four ortho substituents via Suzuki coupling is described. The combination of a catalytic quantity of Pd2(dba)3 with either an electron-rich biarylphosphine or DPEPhos is effective using a wide range of substrates. The X-ray crystal structure of (dba)Pd(2-(9-phenanthryl)phenyl-dicyclohexylphosphine), in which the Pd is coordinated to the 9,10-double bond of the phenanthryl group, is also reported. Copyright